Functionalized Nanomaterials for Catalytic Application

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With the rapid development in nanotechnology, it is now possible to modulate the physical and chemical properties of nanomaterials with molecular recognition and catalytic functional applications. Such research efforts have resulted in a huge number of catalytic platforms for a broad range of analytes ranging from metal ions, small molecules, ionic liquid and nucleic acids down to proteins. Functionalized nanomaterials (FNMs) have important applications in the environmental, energy and healthcare sectors. Strategies for the synthesis of FNMs have contributed immensely to the textile, construction, cosmetics, biomedical and environmental industries among others.
This book highlights the design of functionalized nanomaterials with respect to recent progress in the industrial arena and their respective applications. It presents an inclusive overview encapsulating FNMs and their applications to give the reader a systematic and coherent picture of nearly all relevant up-to-date advancements. Herein, functionalization techniques and processes are presented to enhance nanomaterials that can substantially affect the performance of procedures already in use and can deliver exciting consumer products to match the current lifestyle of modern society.

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This book highlights the design of functionalized nanomaterials with respect to recent progress in the industrial arena and their respective applications. It presents an inclusive overview encapsulating FNMs and their applications to give the reader a systematic and coherent picture of nearly all relevant up-to-date advancements. Herein, functionalization techniques and processes are presented to enhance nanomaterials that can substantially affect the performance of procedures already in use and can deliver exciting consumer products to match the current lifestyle of modern society. Advanced undergraduate and graduate students and industrial professionals will find this book a good source of knowledge that will act as a guideline for their studies and research. Because of the integral nature of the topics, it will also be of interest to a broad spectrum of audiences, including industrial scientists, industrial engineers, nanotechnologists, materials scientists, chemists, physicists, pharmacists, biologists, chemical engineers, and all those who are involved and interested in the future frontiers of nanomaterials. In other words, it was devised as a reference book for researchers and scientists who are searching for new advanced techniques for various catalytic applications.

Among the editors and contributors to this book are prominent researchers, scientists and true professionals from academia and industry. We are very thankful to all the authors of the chapters for the wonderful and passionate effort they displayed while working on this book. And a special thanks to Martin Scrivener and the entire team at Scrivener Publishing for their dedicated support and help during the process of compiling and publishing this book.

Chaudhery Mustansar Hussain, Ph.D. Sudheesh K. Shukla, Ph.D. Bindu Mangla, Ph.D.

1

Functionalized Nanomaterial (FNM)–Based Catalytic Materials for Water Resources

Sreevidya S.1, Kirtana Sankara Subramanian2, Yokraj Katre1, Ajaya Kumar Singh3* and Jai Singh4

1Department of Chemistry, Kalyan PG College, Bhilai Nagar, Durg, India

2Department of Food Science, Faculty of Veterinary and Agriculture Science, University of Melbourne, Melbourne, Australia

3Department of Chemistry, Govt. V.Y.T. PG. Autonomous College, Durg, India

4Department of Pure and Applied Science, Guru Ghasidas Vishwavidyalaya (A Central University), Bilaspur, India

Abstract

Water, one of the essential elements in the nature under a great threat, with pollutants treasured in it generates noxious suffocations with the raise in contaminants globally. It is time we wake up. Fabrication of innovative nanomaterials with unique models and approaches, deliver versatilities in overcoming the drawbacks installed in earlier protocols for a full-scale utilisation in the environmental pitch. Functionalization of nanoscales provides a promising note, when employed in remediation applicational functions for environmental system. Protection of as-synthesized nano scaled material by casing a suitable layer of organics/inorganics on their core surface by functionalization modules enhances the functionalities.

Functionalized nanomaterials supported with nanocatalyst have been proven for their high selectivity and controlled sensitivity over the target samples in water management. Nano-adsorbents, nano-membranes and nanocatalysts are commendably employed for attacking and eliminating the pollutant from the resourceful water sectors either in surface or in sub-surface. Functionalized nanocatalysts like electrocatalyst, photocatalyst, electro-Fenton catalyst, Fenton-based catalyst, and oxidants (chemical) by versatile processes have revealed their potentialities in getting rid of biological, organic and/or inorganic toxicants from water bodies that might lead to painful health issues. Functionalized nanocatalytic materials for remediation of water resources will be mainly focused in the segments to come.

Keywords: Functionalization, nanomaterials, nanocatalyst, pollutants, remediation, water

Abbreviations Used:

Organization
WHO World Health Organization EPA Environmental Protection Agency
Technical
NIR Near Infra-Red ECMR Electrocatalytic Membrane Reactor
PL Photoluminescence LUMO Lowest unoccupied molecular orbital
CB Conduction Band VB Valence Band
e- Electron h + Holes
Functionals
EC Electrocatalyst PC Photocatalyst
EF Electro-Fenton P-EF Photoelectro Fenton
F’bC Fenton-based catalyst H-EF Hetero Electro-Fenton
HF Heterogenous-Fentons H-PF Hetero Photo-Fenton
PF Photo-Fentons pF Photo-Fenton–like
Terminologies
FNMs Functionalized NM Nanomaterials
Nanomaterials
NP Nanoparticles NT Nanotubes
NS Nanosheets NR Nanorods
NF Nanofibers NW Nanowires
TP Target Pollutant OP Organic Pollutant
TOC Total Organic Carbon DP Degraded Products
CNT Carbon nanotubes MWCNT Multiwalled Carbon nanotubes
CNO Carbon nano onion CF C Felt/Fiber
CFP Carbon fiber paper CP Carbon paper
QDs Quantum Dots MNPs Magnetic nanoparticles
CQDs Carbon QDs CDs Carbon dots
Materials
R/r GO Reduced GO ACA Activated C aerogel
GA Graphene aerogels GPCA Graphene polyacrylamide carbonized aerogel
PC Porous C MPCMSs Magnetic porous C micro-spheres
BDD Boron doped diamond Fe-HPAN Fe-loaded hydrolyzed polyacrylonitrile
SS Stainless steel GMSA Glycerol mediated self-assembly
HPC Hollow porous C MMTNS Montmorillonite nanosheets
Fe-POM Fe-polyoxometalates PPy NTs Polypyrole nano-tubes
CNQDs Carbon nitride QDs GCNQDs Graphene-Carbon nitride QDs
TCNCs Tubular Carbon Nitride
Nomenclature:
PANI Polyaniline PTFE Polytetrafluoroethylene
G Graphene CE Cetyl Trimethyl Ammonium Bromide
GO Graphene Oxide EDTA Ethylenediaminetetraacetic acid
PAN Polyacrylonitrile EDC 1-ethyl-3-(3-dimethylamino-propyl) carbodiimide
CS Chitosan PDVF Polyvinylidene difluoride
PHB Poly-hydroxyl butyrate MUC Melamine, Cyanuric acid, Urea
PEG Poly-ethylene glycol ABA 4-aminomethyl benzoic acid
O-TD O-toluidine TCPP Tetrakis (4-carboxyphenyl) porphyrin
SA Salicylic acid L-Cys L-Cystine
2-ME 2-mercaptoethanol PAMAM Poly(amidoamine)
Try L-tryptophan Glu L-glutamic acid
PUF Polyurethane foam
Organic: Pollutant
PCA p-Chloroaniline TCP 2,4,6-trichlorophenol
4-NP p-nitrophenol (PNP) 4-CP 4-chlorophenol
2,4-DCP 2,4-Dichlorophenol DMP dimethyl phthalate
5-TBA 5-tolylbenzotriazole 2,4,5-PCB 2,4,5-trichlorobiphenyl
BPA Bisphenol A
Dyes: Pollutant
MO Methyl Orange MB Methylene Blue
MG Malachite Green CR Congo Red
Rh B Rhodamine B CB Chlorazol black
BG Brilliant Green RR-120 Reactive red 120
EB Evans blue X-3B Reactive Brilliant Red
CV Crystal Violet VBR Victoria blue R
RO-16 Reactive Orange-16 TBAC-L Texbrite BAC-L
TNFW-L Texbrite NFW-L TBBU-L Texbrite BBU-L
Drugs: Pollutant
CIP Ciprofloxacin TC Tetracycline
IBP Ibuprofen TCH Tetracycline-Hydrochloride
CBZ Carbamazepine OTC Oxytetracycline
DFC Diclofenac NPX Naproxen
PCM Paracetamol KP Ketoprofen
CEL Cephalexin
Pesticides: Pollutant
ATZ Atrazine IMI Imidacloprid
ATP Acetamiprid TMX Thiamethoxam
ALA Alachor
Consumer Products
TCS Triclosan

1.1 Introduction

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