Functionalized Nanomaterials for Catalytic Application

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With the rapid development in nanotechnology, it is now possible to modulate the physical and chemical properties of nanomaterials with molecular recognition and catalytic functional applications. Such research efforts have resulted in a huge number of catalytic platforms for a broad range of analytes ranging from metal ions, small molecules, ionic liquid and nucleic acids down to proteins. Functionalized nanomaterials (FNMs) have important applications in the environmental, energy and healthcare sectors. Strategies for the synthesis of FNMs have contributed immensely to the textile, construction, cosmetics, biomedical and environmental industries among others.
This book highlights the design of functionalized nanomaterials with respect to recent progress in the industrial arena and their respective applications. It presents an inclusive overview encapsulating FNMs and their applications to give the reader a systematic and coherent picture of nearly all relevant up-to-date advancements. Herein, functionalization techniques and processes are presented to enhance nanomaterials that can substantially affect the performance of procedures already in use and can deliver exciting consumer products to match the current lifestyle of modern society.

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10 Chapter 11Figure 11.1 Importance of biogenic synthesis.Figure 11.2 Various methods for synthesis of PdNPs.Figure 11.3 Various biosynthesis routes of PdNPs.Figure 11.4 Common phytochemicals present in plant extract.Scheme 11.1 Plausible reduction mechanism of Pd(II) to Pd(0).Figure 11.5 Schematic representation of PdNP applications.Figure 11.6 Synthesis of PdNPs using black pepper plant extract and its characte...Scheme 11.2 PdNPs’ catalyzed cyanation and Hiyama cross-coupling reaction.Scheme 11.3 PdNPs’ catalyzed denitrogenative coupling reaction.Figure 11.7 Synthesis of PdNPs using papaya peel and its characterization (Sourc...Scheme 11.4 PdNPs’ catalyzed Suzuki-Miyaura coupling reaction.Scheme 11.5 PdNPs’ catalyzed Sonogashira cross-coupling reaction.Figure 11.8 Synthesis of PdNPs using watermelon rind and its characterization (S...Scheme 11.6 PdNPs’ catalyzed Suzuki coupling reaction.Figure 11.9 Synthesis of PdNs@PA using waste corn cob and its characterization (...Scheme 11.7 Suzuki coupling reaction catalyzed by cellulose-supported PdNs@PA.Figure 11.10 Synthesis of PdNPs using Pulicaria glutinosa extract and its charac...Scheme 11.8 PdNPs’ catalyzed Suzuki coupling reaction.Figure 11.11 Synthesis of PdNPs using leaf extract of Chrysophyllum cainito and ...Figure 11.12 Synthesis of PdNP@AT-mont using Tulsi leaves and its characterizati...Scheme 11.9 Hydrodechlorination of 4-chlorophenol (4-CP).Figure 11.13 Synthesis of PdNPs using gum olibanum and its characterization (Sou...

11 Chapter 12Figure 12.1 Benefits of nanocatalysts.Figure 12.2 The three categories of nanocatalyst.Figure 12.3 Two major approaches used for fabrication of nanoparticles.Figure 12.4 Some applications of metal-based nanocatalyst in various fields.Figure 12.5 Different types of nano-metal catalysis.Figure 12.6 The major types of metal nanoparticles used for catalysis.Figure 12.7 Pictorial representation of size, structure, and composition depende...

12 Chapter 13Figure 13.1 Publications 2011–2020 containing “nanocatalyst” as topic using SciF...Figure 13.2 Smart paper transformation approach for catalytic separation and reu...Figure 13.3 Journey from bulk materials to single atom catalyst (with copyright ...Scheme 13.1 GO catalyzes the oxidation of alcohols and alkynes, as well as the h...Scheme 13.2 Role of gold and silica quinolone synthesis.Figure 13.4 Illustration of modern polymer electrolyte membrane fuel cell (copyr...

13 Chapter 14Figure 14.1 Classification of carbon dots and proposed structures of graphene qu...Figure 14.2 Various synthetic routes for preparation of carbon dots.Figure 14.3 Schematic illustration of hydrothermal treatment for preparation of ...Figure 14.4 Schematic representation of solvothermal treatment for preparation o...Figure 14.5 Microwave-assisted synthesis of carbon dots from lemon and onion jui...Figure 14.6 Jablonski energy diagram.Figure 14.7 The proposed reaction mechanism for TiO 2/CQDs under visible light. R...Figure 14.8 Synthesis of the carbon dot-carboxymethylcellulose (CMC)-polymerized...Figure 14.9 The proposed reaction mechanism of water splitting by CDs-CdS nanoco...Scheme 14.1 Reduction of CO 2into C1 and C2 products.

List of Illustrations

1 Chapter 1 Table 1.1 Electro-Fenton (EF)/Hetero-Electro-Fenton (H-EF) catalyst as FNMs. Table 1.2 Photo-Fenton (PF)/Photo-Fenton–like (pF) catalyst as FNMs. Table 1.3 Photocatalyst (PC) as FNMs.

2 Chapter 2 Table 2.1 Co-precipitation methods for production of magnetic iron oxide nanocom... Table 2.2 Preparation methods for various functionalized carbon nanomaterials [1... Table 2.3 Common sources of some heavy metals pollution. Table 2.4 Common health problems caused to humans by heavy metals. Table 2.5 Functionalized carbon nanomaterials for the adsorption of heavy metals... Table 2.6 Magnetic iron oxide nanoadsorbents for the removal of heavy metals [84...

3 Chapter 5Table 5.1 Comparison of different FNMs synthesized by following several approach...

4 Chapter 6Table 6.1 Comparison of properties of homogeneous, heterogeneous, and their hybr...Table 6.2 Types of silica material available.Table 6.3 Biopolymer-based Fe NPs [23, 26].

5 Chapter 7Table 7.1 Different nanotechnologies for the detection of heavy metals in water....Table 7.2 Arsenic removal from contaminated water using different nanomaterials....Table 7.3 Lead removal from contaminated water using different nanomaterials.Table 7.4 Cadmium removal from contaminated water using different nanomaterials....Table 7.5 Nickel Removal from contaminated water using different nanomaterials. ...

6 Chapter 8Table 8.1 General classification of nanomaterials and their applications.

7 Chapter 11Table 11.1 Common characterization techniques for PdNPs.

8 Chapter 12Table 12.1 The comparison between the different types of nanomaterials used in c...Table 12.2 The different application nano-metal catalysts.

9 Chapter 13Table 13.1 Organic transformations.Table 13.2 Electro catalysis.Table 13.3 Photo catalysis.

10 Chapter 14Table 14.1 Comparison of characteristics of carbons dots.Table 14.2 Methods of preparation, properties, and applications of carbon dots o...Table 14.3 Summary of merits and demerits of different methods used for biomass ...Table 14.4 Carbon dot-ligand conjugates used for drug delivery.

Guide

1 Cover

2 Table of Contents

3 Title page

4 Copyright

5 Preface

6 Begin Reading

7 Index

8 End User License Agreement

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