Mechanical and Dynamic Properties of Biocomposites

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Mechanical and Dynamic Properties of Biocomposites
A comprehensive review of the properties of biocomposites and their applications Mechanical and Dynamic Properties of Biocomposites
Mechanical and Dynamic Properties of BIocomposites

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1.4.1.3 Banana/Kenaf and Banana/Sisal FRP Hybrid Composites

A good material for reinforcement in diverse polymer composites is the banana fiber. Its extraction is usually from the bark of banana trees [4]. Banana fiber has such advantaged mechanical properties, including good tensile strength and modulus, due to the high content of cellulose and low microfibrillar angle [25]. Kenaf fiber is a promising element of reinforcement in polymer composites, due to its interesting mechanical features such as eco‐friendliness and renewability. Kenaf is usually extracted from bast fiber (kenaf plants) [4]. Sisal, on the other hand, is known to be among the toughest materials for reinforcement. It is also well known for its durability. Sisal FRP composites possess moderate flexural and tensile behaviors and high impact strength, when compared with other composites of natural fiber reinforcements. It has relevant use in some industries, such as agriculture and marine to make twines, ropes, cords, rugs, and bagging, among others [26]. Sisal and kenaf fibers, similar to other natural fibers, have poor interfacial bonding with a polymer matrix, which shows their disadvantage [27].

Table 1.5 Mechanical behaviors of bagasse/jute, bamboo/MFC, and banana/kenaf FRP hybrid composites.

Source: Nguyen et al. [4]. © 2017, Elsevier.

Hybrid biocomposites Fiber ratio (by weight or volume) Flexural modulus (GPa) Flexural strength (MPa) Tensile modulus (GPa) Tensile strength (MPa) Impact strength (kJ/m 2)
Natural fibers
Bagasse/jute Bagasse fiber bundles (untreated) and jute fiber bundles (treated)
0 : 100 0.645 31.15 0.302 11.45 6.90
20 : 80 0.789 36.46 0.356 16.02 7.46
35 : 65 1.101 45.32 0.420 19.45 9.53
50 : 50 1.480 55.63 0.492 23.07 10.66
65 : 35 1.311 51.19 0.399 21.15 8.33
100 : 0 0.502 26.78 0.227 9.87 6.67
Bagasse fiber bundles (treated) and jute fiber bundles (treated)
20 : 80 1.178 42.72 0.526 18.72 10.00
35 : 65 1.484 54.57 0.635 22.57 13.33
50 : 50 1.748 65.22 0.753 26.77 15.93
65 : 35 1.518 60.12 0.704 23.54 10.93
100 : 0 0.632 30.78 0.286 11.20 8.66
Bamboo/MFC MFC/PLA composites (milled to 5 μm)
1 wt.% of MFC 4.61 ± 0.27 45.9 ± 4.1
2 wt.% of MFC 3.95 ± 0.14 51.7 ± 2.3
Banana/kenaf 50 : 50, nonwoven hybrid
10% NaOH treatment 57.2 44 13
10% SLS treatment 60.8 50 16
50 : 50, woven hybrid
10% NaOH treatment 62.0 50 18
10% SLS treatment 68.0 54 21

MFC and PLA represent micro‐fibrillated cellulose and poly‐lactic acid, respectively.

Moreover, Thiruchitrambalam et al. [28] conducted a study on woven as well as non‐woven hybrids of banana/kenaf fiber with unsaturated polyester matrix reinforcement. They kept the fiber contents constant at 40% with equal ratio of banana and kenaf FRP composites (50 : 50 ratio) and treated the fibers with either 10% solution of NaOH or 10% of sodium lauryl sulfate (SLS) for 30 minutes. They observed that the SLS‐treated specimen had better improvement with respect to mechanical behavior than the alkali‐treated specimen, showing for both woven and non‐woven cases of the banana/kenaf hybrid composites enhanced impact, flexural, and tensile strengths, as shown in Table 1.5.

Furthermore, Venkateshwaran et al. [29] evaluated the mechanical properties of banana/sisal FRP epoxy matrix hybrid composite and found out that hybridization increased the flexural, tensile, and impact strengths by 4%, 16%, and 35% respectively. They also reported that the 50 : 50 fiber ratio by weight enhanced the mechanical response of the banana/sisal FRP hybrid composite and decreased the uptake of moisture, as presented in Table 1.6.

1.4.1.4 Coconut/Cork FRP Hybrid Composites

A natural coconut fiber, also known as coir, is usually extracted from coconut trees. These trees are mainly grown in tropical regions of Asian countries, such as Vietnam, India, and Thailand [4]. Cork fiber is usually obtained from cork oak trees ( Quercus suber ). There is a specific species of the tree from whose bark the cork fiber is harvested. The cork oak tree is a renewable resource, as new cork bark regrows naturally [4].

Hybrid composites containing high‐density polyethylene (HDPE) with reinforcements of cork powder and short coconut fibers that were randomly distributed was prepared by Fernandes et al. [30]. The interfacial bonding and compatibility between the matrix and fiber was improved by maleic anhydride, a coupling agent (CA). Their results showed 27% and 47% rise in elastic moduli and tensile strengths of the coconut/HDPE/cork hybrid composites, respectively ( Table 1.6), when compared with the cork/HDPE composite. Also, they observed that using CA resulted in enhancement of the elongation at break and tensile behaviors of the hybrid composites. As a recommendation for better mechanical responses of the cork‐based composites, 10 wt.% of short coconut fibers and 2 wt.% of CA were proposed.

Table 1.6 Mechanical behaviors of banana/sisal, coconut/cork, coir/silk, corn husk/kenafm and cotton/jute FRP hybrid composites.

Source: Nguyen et al. [4]. © 2017, Elsevier.

Hybrid biocomposites Fiber ratio (by weight or volume) Flexural modulus (GPa) Flexural strength (MPa) Tensile modulus (GPa) Tensile strength (MPa) Impact strength (kJ/m 2)
Banana/sisal 100 : 0 8.920 57.33 0.642 16.12 13.25
75 : 25 9.025 58.51 0.662 17.39 15.57
50 : 50 9.130 59.69 0.682 18.66 17.90
25 : 75 9.235 60.87 0.703 19.93 20.22
0 : 100 9.340 62.04 0.723 21.20 22.54
Coconut/cork 10 : 44 : 44 : 2 (wt.% of coconut/cork/HDPE/coupling agent) 0.599 ± 0.02 20.4 ± 0.3
Coir/silk Alkali treatment
10 mm fiber 39.53 15.01
20 mm fiber 45.07 17.24
30 mm fiber 42.02 16.14
Corn husk/kenaf 0 : 30 (PLA 70 wt.%) 2.117
15 : 15 (PLA 70 wt.%) 1.547
30 : 0 (PLA 70 wt.%) 1.221
Cotton/jute 23.7 : 76.3 (jute fabric type III)
Test angle, 0° 9.9 ± 0.8 136.7 ± 4.0 7.1 ± 0.3 59.4 ± 1.7 9.3 ± 0.9
Test angle, 45° 8.4 ± 0.7 84.6 ± 4.7 4.6 ± 0.1 21.1 ± 1.4 7.5 ± 1.0
Test angle, 90° 7.2 ± 0.7 58.3 ± 5.4 4.1 ± 0.1 14.6 ± 0.5 5.5 ± 1.0

HDPE = high‐density polyethylene.

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