F. Xavier Malcata - Mathematics for Enzyme Reaction Kinetics and Reactor Performance

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Enzyme Reactor Engineering
The second volume begins with an introduction to basic concepts in calculus, i.e. limits, derivatives, integrals and differential equations; limits, along with continuity, are further expanded afterwards, covering uni- and multivariate cases, as well as classical theorems. After recovering the concept of differential and applying it to generate (regular and partial) derivatives, the most important rules of differentiation of functions, in explicit, implicit and parametric form, are retrieved – together with the nuclear theorems supporting simpler manipulation thereof. The book then tackles strategies to optimize uni- and multivariate functions, before addressing integrals in both indefinite and definite forms. Next, the book touches on the methods of solution of differential equations for practical applications, followed by analytical geometry and vector calculus. Brief coverage of statistics–including continuous probability functions, statistical descriptors and statistical hypothesis testing, brings the second volume to a close.

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whereas ordered subtraction thereof gives rise to

(2.561) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 681

division of both sides by 2 yields

(2.562) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 682

and

(2.563) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 683

from Eqs. (2.560)and (2.561), respectively – or else

(2.564) from Eq 2562after combination with Eq 2473 as well as 2565 from - фото 684

from Eq. (2.562)after combination with Eq. (2.473), as well as

(2.565) from Eq 2563following combination with Eq 2472 The two basic - фото 685

from Eq. (2.563)following combination with Eq. (2.472). The two basic relationships between hyperbolic and circular functions are consequently conveyed by Eqs. (2.564)and (2.565).

2.4.4 Inverse Functions

Inverse hyperbolic functions are often useful, and will accordingly be discussed next; in the case of sinh −1 x , one should start by setting

(2.566) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 686

so application of hyperbolic sine to both sides gives rise to

(2.567) since composition of a function with its inverse cancels out their mutual - фото 687

– since composition of a function with its inverse cancels out their mutual effects. Insertion of Eq. (2.567)allows transformation of Eq. (2.496)– rewritten in (dummy) variable y , to

(2.568) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 688

so adding x 2to both sides and taking square roots thereof afterward generate

(2.569) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 689

here only the plus sign was kept, since cosh y > 0 as per Fig. 2.14a. Based on Eq. (2.479)rewritten for y , one finds that

(2.570) following combination with Eqs 2567and 2569 or after applying - фото 690

following combination with Eqs. (2.567)and (2.569)– or, after applying logarithms to both sides,

(2.571) that is the same to write 2572 as per Eq 2566 a plot of Eq 2572is - фото 691

that is the same to write

(2.572) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 692

as per Eq. (2.566); a plot of Eq. (2.572)is conveyed by Fig. 2.15a. Note that Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 693, so in view of Eq 22 therefore the argument of the logarithm in Eq 2572is - фото 694in view of Eq. (2.2); therefore, the argument of the logarithm in Eq. (2.572)is always positive, and sinh −1 x is defined for all real numbers.

Figure 215 Variation with their argument x of inverse hyperbolic functions - фото 695

Figure 2.15 Variation, with their argument x , of inverse hyperbolic functions, viz. (a) inverse hyperbolic sine (sinh −1) and cosine (cosh −1) and (b) inverse hyperbolic tangent (tanh −1) and cotangent (cotanh −1).

By the same token, if one sets

(2.573) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 696

then hyperbolic cosine may be applied to both sides to produce

(2.574) again due to the inefficacy with regard to its argument of composing a - фото 697

– again due to the inefficacy, with regard to its argument, of composing a function with its inverse. Upon combination of Eq. (2.496), rewritten for y , with Eq. (2.574), one obtains

(2.575) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 698

where isolation of sinh y yields

(2.576) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 699

– with both signs preceding the square root being now feasible, since sinh y may take either positive or negative values (see Fig. 2.14a); once in possession of Eqs. (2.574)and (2.576), one may resort to Eq. (2.479),with x relabeled as y , to write

(2.577) Application of logarithms to both sides of Eq 2577finally gives 2578 - фото 700

Application of logarithms to both sides of Eq. (2.577)finally gives

(2.578) or else 2579 with the aid of Eq 2573 as depicted also in Fig 215a - фото 701

or else

(2.579) with the aid of Eq 2573 as depicted also in Fig 215a In this case is - фото 702

with the aid of Eq. (2.573), as depicted also in Fig. 2.15a. In this case, Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 703is defined only when x 2 > 1, or else x < − 1 ∨ x > 1; furthermore, Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 704, thus implying that Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 705when x < 1, but Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 706for x > 1 – so only the latter can be taken as domain for cosh −1 x , so that logarithm thereof can be defined. However, so two possible values actually arise ie cosh 1 x is a doublevalued - фото 707, so two possible values actually arise, i.e. cosh −1 x is a double‐valued function; only the positive value of the logarithm is usually considered, thus implying use of the positive sign preceding the square root in its argument.

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