F. Xavier Malcata - Mathematics for Enzyme Reaction Kinetics and Reactor Performance

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Enzyme Reactor Engineering
The second volume begins with an introduction to basic concepts in calculus, i.e. limits, derivatives, integrals and differential equations; limits, along with continuity, are further expanded afterwards, covering uni- and multivariate cases, as well as classical theorems. After recovering the concept of differential and applying it to generate (regular and partial) derivatives, the most important rules of differentiation of functions, in explicit, implicit and parametric form, are retrieved – together with the nuclear theorems supporting simpler manipulation thereof. The book then tackles strategies to optimize uni- and multivariate functions, before addressing integrals in both indefinite and definite forms. Next, the book touches on the methods of solution of differential equations for practical applications, followed by analytical geometry and vector calculus. Brief coverage of statistics–including continuous probability functions, statistical descriptors and statistical hypothesis testing, brings the second volume to a close.

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or else

(2.453) after condensing terms alike ordered subtraction of Eq 2451from Eq - фото 571

after condensing terms alike; ordered subtraction of Eq. (2.451)from Eq. (2.453)generates

(2.454) which breaks down to 2455 upon cancelation of symmetrical terms and - фото 572

which breaks down to

(2.455) upon cancelation of symmetrical terms and which recovers Eq 2443 after - фото 573

upon cancelation of symmetrical terms – and which recovers Eq. (2.443), after swapping 2 ab cos γ and c 2between sides.

Another important relationship in trigonometry relates the lengths of the sides of a triangle of any shape to the sines of its angles, according to

(2.456) it is classically referred to as law of sines or sine formula and a b - фото 574

it is classically referred to as law of sines, or sine formula – and a , b , and c denote lengths of the sides opposing angles α , β , and γ , respectively, while R denotes radius of the circumcircle to the triangle. To derive the first two equalities in Eq. (2.456), one should recall the rule of calculation of the area of a triangle, S – as one half of the product of its base by its height (to be proven later); inspection of Fig. 2.12b indicates that this can be done in three different ways, i.e.

(2.457) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 575

using [ BC ] as base and [ AC ] as hypotenuse,

(2.458) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 576

using [ AC ] as base and [ AB ] as hypotenuse, or

(2.459) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 577

using [ AB ] as base and [ BC ] as hypotenuse – in all cases at the expense of the graphical interpretation of sine conveyed by Eq. (2.290). Since Eqs. (2.457)– (2.459)share their left‐hand side, one may lump them as

(2.460) whereas a further multiplication of all sides by 2 abc permits simplification - фото 578

whereas a further multiplication of all sides by 2/ abc permits simplification to

(2.461) the first two equalities in Eq 2461degenerate to the corresponding - фото 579

the first two equalities in Eq. (2.461)degenerate to the corresponding equalities in Eq. (2.456), after taking reciprocals of all three sides. To prove the last equality of Eq. (2.456), one should redraw triangle [ ABC ] together with the corresponding circumscribed circle – as done in Fig. 2.12c; furthermore, an altitude may be drawn from the center of the circle, O , toward side [ BC ], with intercept denoted as D . Since sides [ OB ] and [ OC ] of auxiliary triangle [ OBC ] are identical for coinciding with radius R of the circle, the altitude [ OD ] of this isosceles triangle splits in half the angle formed by [ OB ] and [ OC ], as well as segment [ BC ] of length a ; therefore, angle ∠ BOD is equal to angle ∠ COD , and to half the angle ∠ BOC – and thus also equal to angle ∠ BAC of amplitude α , because it subtends side [ BC ] with corner A lying on the circle. By definition of sine as ratio of length of opposite leg to that of hypotenuse, one realizes that

(2.462) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 580

pertaining to ∠ BOD , or equivalently

(2.463) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 581

after revisiting Eq. (2.458)as

(2.464) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 582

following isolation of sin α , one may eliminate sin α between Eqs. (2.463)and (2.464)to get

(2.465) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 583

– which degenerates to

(2.466) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 584

when solved for the reciprocal of 2 R . Insertion of Eq. (2.466)transforms Eq. (2.461)to

(2.467) so Eq 2456will be retrieved in full after reciprocals are taken of all - фото 585

– so Eq. (2.456)will be retrieved in full, after reciprocals are taken of all four sides.

Once in possession of Eq. (2.442), one may produce an alias through division of both sides by sin 2 x , viz.

(2.468) which is equivalent to 2469 in view of Eqs 2304and 2314 if - фото 586

which is equivalent to

(2.469) in view of Eqs 2304and 2314 if division of both sides is performed by - фото 587

in view of Eqs. (2.304)and (2.314); if division of both sides is performed by cos 2 x instead, then Eq. (2.442)becomes

(2.470) which may appear as 2471 at the expense of Eqs 2299and 2309 Both - фото 588

– which may appear as

(2.471) at the expense of Eqs 2299and 2309 Both Eqs 2469and 2471may be - фото 589

at the expense of Eqs. (2.299)and (2.309). Both Eqs. (2.469)and (2.471)may be useful, namely when changing variables throughout integration of some types of functions.

Figure 213 Variation with their argument x of major inverse trigonometric - фото 590

Figure 2.13 Variation, with their argument x , of major inverse trigonometric functions, viz. (a) inverse sine (sin −1) and cosine (cos −1), and (b) inverse tangent (tan −1) and cotangent (cotan −1).

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