F. Xavier Malcata - Mathematics for Enzyme Reaction Kinetics and Reactor Performance

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Enzyme Reactor Engineering
The second volume begins with an introduction to basic concepts in calculus, i.e. limits, derivatives, integrals and differential equations; limits, along with continuity, are further expanded afterwards, covering uni- and multivariate cases, as well as classical theorems. After recovering the concept of differential and applying it to generate (regular and partial) derivatives, the most important rules of differentiation of functions, in explicit, implicit and parametric form, are retrieved – together with the nuclear theorems supporting simpler manipulation thereof. The book then tackles strategies to optimize uni- and multivariate functions, before addressing integrals in both indefinite and definite forms. Next, the book touches on the methods of solution of differential equations for practical applications, followed by analytical geometry and vector calculus. Brief coverage of statistics–including continuous probability functions, statistical descriptors and statistical hypothesis testing, brings the second volume to a close.

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(2.409) after taking Eq 2391into account and performing elementary algebraic - фото 515

after taking Eq. (2.391)into account and performing elementary algebraic rearrangement. Insertion of Eq. (2.409), together with realization that ( 1) 2n−2j= (−1) 2n(−1) −2j = (−1) −2j = (−1) 2j(since 2 n and 2 j are even integers) and z 0 = 1, allow transformation of Eq. (2.408)to

(2.410) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 516

with convenient factoring out of Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 517, after having lumped the two summations; upon replacement of 2 j by i for being a dummy counting variable, factoring out 2 in the exponents afterward, and splitting the power in denominator, Eq. (2.410)becomes

(2.411) Equation 2383may again be invoked to transform Eq 2411to 2412 while - фото 518

Equation (2.383)may again be invoked to transform Eq. (2.411)to

(2.412) while the denominator was rewritten as a product of composite powers where ι - фото 519

while the denominator was rewritten as a product of composite powers – where ι 2 = − 1 can be used to generate

(2.413) cancelation of 1 nbetween numerator and denominator and factoring out of - фото 520

cancelation of ( 1) nbetween numerator and denominator, and factoring out of 2 in the former unfold

(2.414) since 1 incoincides with 1 niand x is more generally used as argument - фото 521

since ( 1) i−ncoincides with (−1) n−iand x is more generally used as argument than angle θ (as long as rad is employed as units).

In the case of an odd exponent, Eq. (2.407)may be rephrased as

(2.415) based on change of n to 2 n 1 and likewise of i to 2 i 1 complemented by - фото 522

based on change of n to 2 n + 1, and likewise of i to 2 i + 1, complemented by splitting of the summation in two halves and rearrangement of exponents wherever appropriate; recalling Eq. (2.399), one obtains

(2.416) as alternative form for the second summation in Eq 2415 where condensation - фото 523

as alternative form for the second summation in Eq. (2.415), where condensation of terms alike meanwhile took place. In view of Eq. (2.391)pertaining to the symmetry of binomial coefficients, one may proceed to

(2.417) as new version of Eq 2416 which may be inserted in Eq 2415to generate - фото 524

as new version of Eq. (2.416)– which may be inserted in Eq. (2.415)to generate

(2.418) where 1 2n 1 2 n 1 n 1 was taken into account after factoring - фото 525

where ( 1) 2n = (−1 2) n = 1 n = 1 was taken into account after factoring out, ( 1) −2jwas rewritten as (−1)(−1) −2j−1 = −(−1) −(2j + 1), and Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 526was in turn factored out; once 2 j + 1 is replaced by i as (dummy) variable in the outstanding summation and ι 2is replaced by 1, Eq. (2.418)simplifies to

(2.419) along with rewriting of exponent 2 n 1 2 i as 2 n i 1 and 2 2n1as - фото 527

along with rewriting of exponent 2 n + 1 − 2 i as 2( ni ) + 1 and 2 2n+1as twice 2 2n, as well as lumping of powers of 1 between numerator and denominator. After retrieving Eq. (2.384)and replacing n by 2( ni ) + 1, one may reformulate Eq. (2.419)to

(2.420) in view of 1 in 11 in 1 niand 2 2n 2 2 n which may - фото 528

in view of (−1) i−n = 1/(−1) i−n = (−1) n−iand 2 2n = (2 2) n, which may instead look like

(2.421) as more usual form using x expressed in rad as independent variable rather - фото 529

as more usual form – using x (expressed in rad ) as independent variable rather than θ ; Eqs. (2.414)and (2.421)accordingly permit calculation of an (integer) power of sine of any argument as a linear combination of cosines or sines of multiples of said argument.

The converse problem of expressing sines and cosines of in terms of powers of sin θ and cos θ may also be solved via de Moivre’s theorem; one should accordingly retrieve Eq. (2.369), and expand its left‐hand side via Newton’s binomial formula as

(2.422) where advantage was meanwhile taken of ι 2 1 ι 3 ι ι 4 1 and Eq - фото 530

– where advantage was meanwhile taken of ι 2 = − 1, ι 3 = −ι , ι 4 = 1, and Eq. (2.236). Following inspection of the forms of the terms in the right‐hand side of Eq. (2.422), one realizes that ι may be factored out to get

(2.423) a more condensed notation is however possible according to 2424 Equation - фото 531

a more condensed notation is, however, possible according to

(2.424) Equation 2424may be rewritten as 2425 in the case of an even multiple - фото 532

Equation (2.424)may be rewritten as

(2.425) in the case of an even multiple of θ materialized via replacement by 2 n - фото 533

in the case of an even multiple of θ , materialized via replacement by 2 n ; and alternatively

(2.426) when said multiple is odd ie consubstantiated in 2 n 1 Note that no need - фото 534

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