F. Xavier Malcata - Mathematics for Enzyme Reaction Kinetics and Reactor Performance

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance
Enzyme Reactor Engineering
The second volume begins with an introduction to basic concepts in calculus, i.e. limits, derivatives, integrals and differential equations; limits, along with continuity, are further expanded afterwards, covering uni- and multivariate cases, as well as classical theorems. After recovering the concept of differential and applying it to generate (regular and partial) derivatives, the most important rules of differentiation of functions, in explicit, implicit and parametric form, are retrieved – together with the nuclear theorems supporting simpler manipulation thereof. The book then tackles strategies to optimize uni- and multivariate functions, before addressing integrals in both indefinite and definite forms. Next, the book touches on the methods of solution of differential equations for practical applications, followed by analytical geometry and vector calculus. Brief coverage of statistics–including continuous probability functions, statistical descriptors and statistical hypothesis testing, brings the second volume to a close.

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after replacement of n by 2 n as upper limit, and concomitant replacement of i by 2 i as counting variable of the summation – with subsequent splitting of the said summation, so as to make the median term appear explicitly. At this stage, it is convenient to revisit Eq. (2.240)and realize that

(2.390) following straightforward algebraic manipulation in other words 2391 - фото 494

following straightforward algebraic manipulation; in other words,

(2.391) ie the row entries of Pascals triangle are symmetrical relative to its - фото 495

– i.e. the row entries of Pascal’s triangle are symmetrical relative to its median (see Table 2.1). On the other hand, one may introduce a new counting variable satisfying

(2.392) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 496

so that the second summation in Eq. (2.389)can be algebraically converted to

(2.393) In view of Eq 2391 one may reformulate Eq 2393to 2394 which in - фото 497

In view of Eq. (2.391), one may reformulate Eq. (2.393)to

(2.394) which in turn supports conversion of Eq 2389to 2395 upon lumping - фото 498

– which, in turn, supports conversion of Eq. (2.389)to

(2.395) upon lumping of summations for sharing the same lower and upper boundaries - фото 499

upon lumping of summations for sharing the same lower and upper boundaries, coupled with factoring out of in their kernel one may now replace dummy variable 2 j by merely i and - фото 500in their kernel; one may now replace dummy variable 2 j by merely i , and factor out 2 in the exponents of z and 1/ z to get

(2.396) along with definition of a composite power Equation 2383may finally be - фото 501

along with definition of a composite power. Equation (2.383)may finally be invoked to rewrite Eq. (2.396)as

(2.397) after having the original n replaced by 2 n i as well as 2 taken off the - фото 502

after having the original n replaced by 2( ni ), as well as 2 taken off the outstanding summation; θ was also relabeled as x , provided that rad is used.

If the exponent of cosine in Eq. (2.388)is an odd integer, say, 2 n+ 1, then one gets

(2.398) upon replacement of n by 2 n 1 and accordingly of i by 2 i 1 the - фото 503

upon replacement of n by 2 n + 1, and accordingly of i by 2 i + 1; the summation was meanwhile rewritten as two consecutive summations, while z in the first summation gave the floor to its reciprocal at the expense of taking the negative of the exponent. A new change of variable, viz.

(2.399) inspired on Eq 2392 proves useful to transform the second summation in - фото 504

– inspired on Eq. (2.392), proves useful to transform the second summation in Eq. (2.398)to

(2.400) where condensation of terms alike meanwhile took place Eq 2391may then be - фото 505

where condensation of terms alike meanwhile took place; Eq. (2.391)may then be used to transform Eq. (2.400)to

(2.401) while insertion of Eq 2401in Eq 2398further leads to 2402 with - фото 506

– while insertion of Eq. (2.401)in Eq. (2.398)further leads to

(2.402) Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 507

with summations pooled together on the basis of their similarity, and Mathematics for Enzyme Reaction Kinetics and Reactor Performance - изображение 508factored out afterward. Since 2 j + 1 is a dummy (counting) variable, it may be swapped for just i , thus allowing reformulation of Eq. (2.402)to

(2.403) where 2 was meanwhile factored out in the exponents in view of Eq - фото 509

where 2 was meanwhile factored out in the exponents; in view of Eq. (2.383)again – after exchanging exponent n by 2( ni ) + 1, one finds

(2.404) as alternative version of Eq 2403 also with the aid of 2 2nbeing identical - фото 510

as alternative version of Eq. (2.403)– also with the aid of 2 2nbeing identical to the n th power of 2 2. Since 2 can cancel out between numerator and denominator, Eq. (2.404)becomes simply

(2.405) after renaming angle θ to x expressed in rad all in all an integer power - фото 511

after renaming angle θ to x (expressed in rad ); all in all, an integer power of the cosine of an angle x may be expressed as a (finite) sum of cosines of integer multiples of x – see Eqs. (2.397)and (2.405).

With regard to the power of any sine, Eq. (2.386)may be similarly revisited with the aid of Newton’s binomial, labeled as Eq. (2.236), to get

(2.406) lumping of the powers of z and 1 z supports transformation to 2407 Should - фото 512

lumping of the powers of z and 1/ z supports transformation to

(2.407) Should the exponent of sine be an even integer Eq 2407transforms to - фото 513

Should the exponent of sine be an even integer, Eq. (2.407)transforms to

(2.408) once n and i are replaced by 2 n and 2 i respectively where terms were - фото 514

once n and i are replaced by 2 n and 2 i , respectively – where terms were deliberately grouped according to 2 i < n , 2 i = n and 2 i > n , and variable z swapped for 1/ z at the expense of a minus sign in the original exponent; variable 2 j as per Eq. (2.392)may now be retrieved to rewrite the second summation as

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