Encyclopedia of Glass Science, Technology, History, and Culture

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A comprehensive and up-to-date encyclopedia to the fabrication, nature, properties, uses, and history of glass
 
The
has been designed to satisfy the needs and curiosity of a broad audience interested in the most varied aspects of material that is as old as the universe. As described in over 100 chapters and illustrated with 1100 figures, the practical importance of glass has increased over the ages since it was first man-made four millennia ago. The old-age glass vessels and window and stained glass now coexist with new high-tech products that include for example optical fibers, thin films, metallic, bioactive and hybrid organic-inorganic glasses, amorphous ices or all-solid-state batteries. 
In the form of scholarly introductions, the Encyclopedia chapters have been written by 151 noted experts working in 23 countries. They present at a consistent level and in a self-consistent manner these industrial, technological, scientific, historical and cultural aspects. Addressing the most recent fundamental advances in glass science and technology, as well as rapidly developing topics such as extra-terrestrial or biogenic glasses, this important guide:
Begins with industrial glassmaking Turns to glass structure and to physical, transport and chemical properties Deals with interactions with light, inorganic glass families and organically related glasses Considers a variety of environmental and energy issues And concludes with a long section on the history of glass as a material from Prehistory to modern glass science The
has been written not only for glass scientists and engineers in academia and industry, but also for material scientists as well as for art and industry historians. It represents a must-have, comprehensive guide to the myriad aspects this truly outstanding state of matter.

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25 Chapter 4.5Table 1 Glass chemical compositions.Table 2 Thermal diffusivity values and fitting parameters for selected glasse...Table 3 Thermal conductivities of selected glasses and liquids.

26 Chapter 5.1Table 1 Reproducibility of XRF analyses (wt %).Table 2 Reproducibility of ICP‐OES analyses (wt %).Table 3 Comparison between hydrolytic‐resistance tests made for a F‐bearing g...Table 4 Defect in a float glass as revealed by anomalous chemical analyses ma...

27 Chapter 5.3Table 1 Melt components in the Ghiorso–Carmichael model and calculation of th...Table 2 Thermodynamic data of fictive components k employed to represent the c...Table 3 Scaling particle theory energy terms [28]. The cavitation enthalpy at

28 Chapter 5.5Table 1 Solubility (mol %) of H 2O, CO 2, and SO 2in NaAlSi 3O 8composition melt...

29 Chapter 5.7Table 1 Original (pre‐2002) values of γ Mfor cations aand Λ for binary ox...Table 2 Relationship of redox ratio, R , for ion couples with optical basicity;...Table 3 Electronegativity, x M, polarizability, α M, and α oxide(‐II)...

30 Chapter 5.11Table 1 Summary of some tests made to determine glass durability.

31 Chapter 5.12Table 1 Chemical‐gradient widths (nm) of boron profiles in surface altered la...

32 Chapter 6.2Table 1 Glass coloring mechanisms.Table 2 Color yielded by various transition metal ions in glasses.

33 Chapter 6.3Table 1 Electron configuration of some transition metal and rare earth elemen...Table 2 Prominent examples of laser‐active glasses.Table 3 Sensitizer–activator combinations in some laser glasses.

34 Chapter 6.4Table 1 Representative properties for common optical fiber glasses.

35 Chapter 6.5Table 1 Composition and main physical properties of fluoride and chalcogenide...

36 Chapter 6.6Table 1 Calculated ( τ R) and measured( τ m) lifetimes and quantum effi...Table 2 Spectroscopic properties of Tm 3+in various glasses [6].Table 3 Measured lifetimes ( τ m) of the Ho 3+: 5I 5level at 293 K for cha...Table 4 Coordination numbers ( N ), bond distances ( R ), and Debye–Waller factor...Table 5 Bohr exciton radii ( a B), band‐gap energies ( E g), and wavelengths ( λ ...Table 6 Compositions and preparation of PbS‐, PbSe‐, and PbTe‐doped glasses.

37 Chapter 6.9Table 1 Chemical composition of glasses for lighting.

38 Chapter 6.10Table 1 Chemical composition (wt %) of glasses for color cathode‐ray tubes.Table 2 Effect of cation atomic weight on the mass absorption coefficients of...Table 3 Chemical compositions (wt %) of frit glasses for PDP.Table 4 Properties of glass substrates for thin‐film transistor liquid‐crysta...Table 5 Properties of glass substrates for plasma‐display panels.

39 Chapter 7.1Table 1 Extraterrestrial glass compositions.

40 Chapter 7.2Table 1 Composition of some natural glasses and average compositions of some ...Table 2 Trace element composition of obsidians from Mediterranean and Near Ea...

41 Chapter 7.4Table 1 The required functions of the slag and important physical properties ...Table 2 Typical compositions for slags from different processes.Table 3 Comparison of approximate property values at specified temperatures f...

42 Chapter 7.5Table 1 Composition and properties of liquid alkaline silicate water glasses ...

43 Chapter 7.6Table 1 Approximate composition (wt %) of representative borosilicate glasses...

44 Chapter 7.7Table 1 Composition ranges of type I and III pharmaceutical glasses (type II ...Table 2 Comparison between glass grain test results for borosilicate glass tu...Table 3 Typical surface test results for type I vials produced by different g...Table 4 Inductively coupled plasma mass spectrometry (ICP‐MS) analyses of ele...

45 Chapter 7.8Table 1 Properties of oxynitride glasses.

46 Chapter 7.9Table 1 Example thermal and optical properties of binary phosphate glasses.Table 2 Examples of phosphate glass phosphors.Table 3 Degradation rates of phosphate glasses containing different modifiers...

47 Chapter 7.10Table 1 Representative metallic glasses: alloy systems and important mechanic...Table 2 Room‐temperature electrical conductivity, thermal diffusivity, and th...Table 3 Mechanical strength and fatigue data of bulk metallic glasses tested ...

48 Chapter 7.11Table 1 Representative compositions of a few commercial glass‐ceramics [6].Table 2 Properties of a few commercial glass‐ceramics.Table 3 Composition and properties of a few noncommercial glass‐ceramics.Table 4 Chemical formula of the main crystalline phases mentioned in this cha...

49 Chapter 8.2Table 1 Advantages of the sol–gel process.Table 2 Drawbacks of the sol–gel process.

50 Chapter 8.3Table 1 Hydrophobic silica aerogel properties.

51 Chapter 8.4Table 1 Selected bioactive glass compositions (mol %), network connectivity o...

52 Chapter 8.5Table 1 Properties of IPS Empress® CAD (scientific report of November 2006, I...

53 Chapter 8.8Table 1 Density, glass transition and melting temperatures, ultimate tensile ...Table 2 Values of the reactivity ratios r 1,2and resulting polymer architectur...Table 3 Macroscopic properties of the stereoisomers of poly(propylene) and po...Table 4 Influence of chain flexibility on T g[3].Table 5 Effect of side chains on T gfor a series of methacrylates [2].

54 Chapter 8.9Table 1 Comparison of inorganic and hybrid sol–gel processes/materials (commo...Table 2 Overview of properties of hybrid polymers.

55 Chapter 9.3Table 1 Examples of mineral wool compositions (wt %).Table 2 Composition (wt %) of wool fibers (produced by cascade process) and c...

56 Chapter 9.5Table 1 Li +ion and Na +ion conductivities for typical oxide and sulfide soli...

57 Chapter 9.6Table 1 Early key technological milestones for flat glass.Table 2 Key technological milestones from the mid‐eighteenth to the mid‐ninet...Table 3 Key milestones from the 1960s to 2014 in process and product developm...Table 4 Key improvements from 1962 to 2014 on coatings, tempering, laminating...Table 5 Main usages of flat glass.Table 6 Key figures about flat‐glass products.Table 7 Foundation of some of the key flat‐glass companies.Table 8 Main producers of float glass in 1988 [9].Table 9 Main producers of float glass in 2015.

58 Chapter 9.7Table 1 End‐ and cross‐fired regenerative furnaces.Table 2 Summary of other furnaces.Table 3 Bath depths: typical ranges and [in brackets] extreme values (mm). aTable 4 Correlation between CO and NO xcontents.

59 Chapter 9.8Table 1 Characteristic dwell times τ i, exponents m i, and effective volume...

60 Chapter 9.9Table 1 2007 European statistics for glass cullet. End‐of‐waste (EoW) criteri...Table 2 2014 EU‐28 recycling rates.Table 3 Glass recovered and discarded in 2013 in the United States. Figures e...Table 4 Origin and possible applications for cullet.Table 5 Scrap from mono‐material collection in bottle banks (unpublished SSV ...Table 6 Scrap from multi‐material collection in bottle banks (unpublished SSV...

61 Chapter 9.10Table 1 Overall chemical compositions of municipal waste incineration ash [2]...Table 2 Mineralogical and chemical composition of municipal waste incineratio...Table 3 Composition of scrap glass in MSWI bottom ash (SP‐1 in Figure 3) and ...Table 4 Chemical composition of fly‐ash particles (wt %, electron microprobe ...

62 Chapter 9.11Table 1 Spent fuel and HLW inventory data.Table 2 Thermal power of R7T7 glass from α, β , and γ emitters o...Table 3 Composition of reference fission product solution vitrified in R7 and...Table 4 Composition of nuclear waste containment glasses (wt %).Table 5 Physical properties of R7T7 glass.Table 6 Summary of characteristics of high‐level waste vitrification faciliti...

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