Jean-Claude Amiard - Management of Radioactive Waste

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Management of Radioactive Waste: краткое содержание, описание и аннотация

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The classification of radioactive waste varies from state to state. This results in different management procedures for each country, while following IAEA and OECD/NEA recommendations.<br /><br />Radioactive waste comes from numerous sources. The largest volumes are generated by the decommissioning and dismantling of nuclear facilities. Long-lived, medium- and high-activity waste – categorized as the most hazardous types of waste – are in fact largely produced by nuclear power reactors, spent fuel reprocessing plants and nuclear accidents.<br /><br />Final disposal of very low-activity, low-activity and very short-lived waste is well controlled. However, final solutions for certain categories, including long-lived waste, sorted waste and spent graphite waste, are not yet in place.<br /><br /><i>Management of Radioactive Waste</i> reviews all the possible solutions and presents those chosen by the various states, including a chapter detailing policy on radioactive waste management, taking France as an example.

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Radionuclide Class A Class B Class C
3H 40 MC MC
14C 0.8 8
60Co 700 MC MC
90Sr 0.04 150 7,000
99Tc 0.3 3
129I 0.008 0.08
137Cs 1 44 4,600
All radionuclides with half-life <5 years 700 MC MC
α emitters with a half-life >5 years 10 100
241Pu 350 3,500
242Cm 2,000 20,000

1.3.5. British classification

The British classification of radioactive waste adopts the IAEA classification into five categories by defining its own criteria for activity levels ( Table 1.3).

Table 1.3. The British nuclear waste classification system (source: [OJO 14, RAH 15])

Waste classes Characteristics of this class
VLLW, small volume Waste of 0.1 m 3that can be disposed of with regular garbage if it contains less than 400 kBq of activity, as well as hospital and university waste. For waste containing carbon-14 and tritium, the activity limit is 4,000 kBq
VLLW, large volume Radioactive waste with an upper limit of 4 MBq per ton (not including tritium) is disposed of in specified landfills. For waste containing tritium, the upper limit is 40 MBq per ton
LLW Containing radioactive material other than that suitable for disposal with ordinary waste, but not exceeding 4 GBq per ton of waste or 12 GBq per ton of β and γ activity
ILW Waste with radioactivity levels above the upper limits for LLW, but which does not generate heat
HLW Wastes in which the temperature can increase significantly due to their radioactivity, so this factor must be taken into account in the design of storage or disposal facilities

1.3.6. Russian classification

The Russian classification of radioactive waste is based on a division into three classes according to the specific activity of various categories of radionuclides ( Table 1.4). The limits of the categories are high.

Table 1.4. Practical classification of radioactive waste in Russia (source: [OJO 14])

Category Specific activity (Bq.g -1)
Tritium Beta (except 3H) Alpha (except transuranium elements) Transuranium elements
Low activity 10 6–10 7 <10 3 <10 2 <10
Average activity 10 7–10 11 10 3–10 7 10 2–10 6 10–10 5
High activity >10 11 >10 7 >10 6 >10 5

1.3.7. Comparisons of the various classifications

Various comparisons can be made between the classifications of radioactive waste used by different countries.

1.3.7.1. American classification and IAEA recommendation

The classification recommended by the IAEA and that applied by the United States have no overlap ( Table 1.5).

Table 1.5. Comparison of IAEA ([IAE 09a], GSG-1) and NRC ([NRC 15]) classifications (source: [NEA 16a])

NRC Class A Class B Class C Excess C or GTCC
IAEA VLLW LLW ILW HLW

1.3.7.2. Comparison between the Belgian, French and Canadian radioactive waste classifications

In Belgium, class A waste has a specific destination and class B and C waste are managed together. In France, the VLLW and LLW-SL categories are managed together, the AA-LL and HALL categories are managed together, while the FA-VL category is managed independently. For the three states, a distinction is made between current waste and historical waste [PAR 18].

Table 1.6. Comparison of radioactive waste classifications in Belgium, France and Canada (source: [PAR 18]). In brackets, the equivalences with the IAEA classification from 2009 [IAE 09a]

Belgium France Canada
Number of categories 3 5 4
Classification by lifespan and activity level A (LLW)B (ILW)C (HLW) TFA (VSLW)FMA-VC (LLW)FA-VL (VLLW)MA-VL (ILW)HA-VL (HLW) LLW (LLW)ILW (ILW)HLW (HLW + spent fuel)Mining waste
Other more vague categories NORM, T-NORMRadiferWaste from future sanitationSpent fuelSpent MOX fuel Waste without a channelFuel and MOX

1.3.8. Classification of sealed sources

For sealed sources, the IAEA [IAE 09a] recommends the classifications reported in Table 1.7.

Table 1.7. Examples of the use of the IAEA classification for disused sealed radioactive sources (source: [IAE 09a])

Type Half-life Activity Volume Examples
VSLW <100 days 100 MBq Small 90Y, 198Au (brachytherapy)
VSLW <100 days 5 TBq Small 192Ir (brachytherapy)
LLW <15 years <10 MBq Small 3H, 60Co, 85Kr
ILW <15 years <100 TBq Small 60Co (irradiators)
LLW <30 years <1 MBq Small 137Cs (brachytherapy)
ILW <30 years <1 PBq Small 90Sr (thickness gauges, thermoelectric generators), 137Cs (irradiators)
ILW >30 years <40 MBq Small but with a large number of sources Pu, Am, Ra (static eliminators)
ILW >30 years <10 GBq 226Ra, 241Am (gauges)

1.4. Origins of nuclear waste

Radioactive waste has multiple origins, which can be subdivided into three main sources: waste from the fuel cycle contributing to nuclear electricity (NFC, Nuclear Fuel Cycle), waste from other very varied origins (medicine, research, etc.) and waste resulting from a nuclear accident. Fuel cycle waste differs according to whether it comes from upstream or downstream plants or from nuclear power reactors in operation ( Figure 1.2).

Figure 12 Diagram of the origins of radioactive waste source OJO 14 - фото 5

Figure 1.2. Diagram of the origins of radioactive waste (source: [OJO 14]). HLW: high-level waste; ILW: intermediate-level waste; LLW: low-level waste; NFC: nuclear fuel cycle; SRS: sealed radioactive sources. For a color version of this figure, see www.iste.co.uk/amiard/radioactive.zip

1.4.1. The main radionuclides in radioactive waste

The principal radionuclides in radioactive waste are very varied and can be classified into four categories. These are fission products (H, Se, Br, Kr, Rb, Sr, Y, Mo, Tc, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, I, Xe, Cs, Ba, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb and Dy), activation products (C, Cr, Mn, Fe, Co, and Ni) and heavy nuclei (U, Nb and Zr), those that are both fission and activation products (Zr and Nb), heavy nuclei (U, Np, Pu, Am and Cm) and some elements with long-lived radioactive isotopes (C, Zr, Tc, Pd, Sn, I, Cs and Sm) to which are added the five heavy nuclei elements.

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