R. N. Kumar - Adhesives for Wood and Lignocellulosic Materials

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The book is a comprehensive treatment of the subject covering a wide range of subjects uniquely available in a single source for the first time. A material science approach has been adopted in dealing with wood adhesion and adhesives. The approach of the authors was to bring out hierarchical cellular and porous characteristics of wood with polymeric cell wall structure, along with the associated non-cell wall extractives, which greatly influence the interaction of wood substrate with polymeric adhesives in a very unique manner not existent in the case of other adherends. Environmental aspects, in particular formaldehyde emission from adhesive bonded wood products, has been included. A significant feature of the book is the inclusion of polymeric matrix materials for wood polymer composites.

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23. Halliwell, B., Lignin synthesis: The generation of hydrogen peroxide and superoxide by horseradish peroxidase and its stimulation by manganese (II) and phenols. Planta, 140, 81–88, 1978.

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30. Jakal, L., Effect of the penetration of adhesive on the strength of adhesion. Faipar, 34, 2, 59–60, 1984.

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Chapter 2 Fundamentals of Adhesion

2.1 Introduction

Adhesion is a multidisciplinary science involving various subjects such as rheology, materials science, organic chemistry, polymer science, and mechanics. Study of fundamentals of adhesion is essential as it leads to better understanding of the factors controlling the performance of the bonded assemblies [1].

Wood is a complex substrate, and it is hard to understand why some adhesives work better than other adhesives, especially under stringent durability tests.

The recent trend in the wood industry is to use smaller-diameter logs and employ other lignocellulosic raw materials to produce more versatile and environmentally acceptable green engineered wood products. This in turn increases the complexity in the choice of adhesives. In order to provide a scientific basis to make the correct choice of adhesives and their formulations, a study of the fundamentals of adhesion is essential.

A clear understanding of wood adhesion mechanisms will enable production of better adhesive and formulation systems suitable for a wider array of wood composite materials. The study of the fundamentals of wood adhesion is essentially distinctive and unique and involves multidisciplinary sciences with respect to both the adherend, the adhesives, and their interactions. The uniqueness of wood as an adherend by virtue of possessing a hierarchical structure has already been dealt with in detail in Chapter 1. In this respect, wood differs significantly from other substrates such as metals, plastics, elastomers, etc. Surface science, rheology, materials science, surface chemistry and surface morphology, organic chemistry, polymer science and polymer characterization, and solid mechanics and interaction between polymers and wood—all contribute to the development and understanding of the adhesion phenomenon.

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