Fuad Nesf Alasfour - Introduction to Desalination

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One book dealing with the fundamentals of thermal and membrane desalination systems and discussing their economical as well as environmental aspects. <br> <br> With a growing population, climate change and greater water demand, desalination has increasingly become a part of the solution to regional water scarcity – seawater desalination capacity has roughly doubled in the past ten years. Desalination has also begun to receive more attention in academia, with research focusing on improving energy efficiency and system robustness and lowering capital costs.<br> <br> With this book, an introduction is given to the basics and fundamentals of desalination systems. Both, thermal and membrane desalination systems, are covered and discussed in view of energy, exergy, economic and environmental aspects. In the beginning, Introduction to Desalination: Systems, Processes and Environmental Impacts describes multi effect evaporation, vapor compression and multi-stage flashing. Further chapters deal with common membrane-based separations like reverse osmosis and membrane filtration, forward osmosis, diffusion dialysis and pervaporation as well as thermo-osmosis, electrodialysis and electrodeionization. Subsequently, hybrid systems are discussed, and the economic analysis of such systems and their environmental impact are highlighted. Each chapter contains theoretical and practical examples and concludes with questions and problems for self-study.<br> <br> * Needed: Desalination has become a part of the solution to regional water scarcity and an introductory book in this field is urgently needed.<br> <br> * Balanced Approach: Presents the fundamentals of thermal and membrane desalination systems.<br> <br> * Learning Material: Each chapter includes exercises for self-study and Instructors can find teaching material online.<br> <br> Introduction to Desalination: Systems, Processes and Environmental Impacts is an important resource for master's students in engineering sciences, lecturers in chemical and mechanical engineering, engineers, environmental chemists, as well as process engineers, engineering scientists in industry, and environmental consultants.<br> <br> <br>

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MEE MSF MEE‐TVC MVC RO ED
Typical unit size (m 3/d) 5000–15 000 50 000–70 000 10 000–35 000 100–2500 24 000 −145 000
Steam pressure (atm) 0.2–0.4 2.5–3.5 0.2–0.4
Electrical energy consumption (kWh/m 3) 1.5–2.5 4–6 1.5–2.5 7–12 3–7 2.6–5.5
Thermal energy consumption (kJ/kg) 230–390 190–390 145–390 None None None
Electrical equivalent for thermal energy (kWh/m 3) 5–8.5 9.5–19.5 9.5–25.5 None None None
Total equivalent energy consumption (kWh/m 3) 6.5–11 13.5–25.5 11–28 7–12 3–7 26–5.5

1.6 Thermo‐Physical Properties of Water

1.6.1 Potable Water

Potable water (freshwater) is characterized with salinity less than 500 ppm.

Table 1.2shows water classification based on salinity, and the standards of WHO for freshwater limit is 500 ppm (0.05 mg/kg).

Table 1.2Water classification based on salinity content.

Type Total dissolved salts (TDS)
Freshwater <1500
Brackish water 1500–10 000
Salt water >10 000
Seawater 10 000–45 000
Standard seawater 35 000

The chemical concentration in fresh water with 500 ppm are shown in Table 1.3.

Table 1.3 Secondary drinking water regulation [5].

Chemicals SDWR
Aluminum 0.05–0.2 mg/l
Chloride 250 mg/l
Color 15 color units
Copper 1.0 mg/l
Corrosivity Non‐corrosive
Fluoride 2.0 mg/l
Foaming agents 0.5 mg/l
Iron 0.3 mg/l
Manganese 0.05 mg/l
Odor Three threshold odor numbers
pH 6.5–8.5
Silver 0.1 mg/l
Sulfate 250 mg/l
Total dissolved solids (TDS) 500 mg/l
Zinc 5 mg/l

Tables 1.3and 1.4show the 2018 Drinking Water Standards and Health Advisories, Secondary Drinking Water Regulations.

Table 1.4WHO standards for potable water [5].

Constitutes Concentration (ppm)
Limited values Max allowed values
Total dissolved salts (TDS) 500 1500
Cl 200 600
SO 4 2+ 200 400
Ca 2+ 75 100
Mg 2+ 30 150
F − 0.7 1.7
NO 3− <50 100
Cu 2+ 0.05 1.5
Fe 3+ 0.10 1.0
NaCl 250
pH 7–8 6.5–9

Table 1.5Thermo‐physical properties of typical seawater at 40 000 ppm and 20 °C.

Density 1.0288 kg/m 3
Specific heat capacity 3.973 kJ/(kg °C)
Boiling point elevation, at 20 °C 0.344 K
Boiling point elevation, at 90 °C 0.565 K
Thermal conductivity 0.601 W/(m K)
Dynamic viscosity 1.089 × 10 −3kg/(m 2s)
Kinematic viscosity 10.58 × 10 −7m 2/s
Latent heat of vaporization 2355.4 kJ/kg

1.6.2 Seawater

Table 1.5shows thermo‐physical properties of standard seawater at 40 000 ppm and 25 °C.

Note that the comprehensive thermo‐physical properties of seawater as a function of temperature and salinity are presented in Appendix A.

The major six elements that comprise about 99% of seawater are chlorine (Cl −), sodium (Na +), sulfate (SO 4 2−), magnesium (Mg +2), calcium (Ca +2), and potassium (K +), and standard seawater composition at 35 000 ppm are presented in Table 1.6.

Table 1.6Standard seawater composition at salinity equal to ≈35 000 ppm.

Chemical ion Concentration (ppm) Valence Total salt content (%) mmol/kg Molecular weight
Chlorine Cl − 19 345 −1 55.03 546 35.453
Sodium Na + 10 752 +1 30.59 468 22.990
Sulfate SO 4 2− 2701 −2 7.68 28.1 96.062
Magnesium Mg 2+ 1295 +2 3.68 53.3 24.305
Calcium Ca 2+ 416 +2 1.18 10.4 40.078
Potassium K + 390 +1 1.11 9.97 39.098
Bicarbonate HCO 3 − 145 −1 0.41 2.34 61.016
Bromide Br − 66 −1 0.19 0.83 79.904
Borate BO 3 3− 27 −3 0.08 0.46 58.808
Strontium Sr 2+ 13 +2 0.04 0.091 87.620
Fluoride F − 1 −1 0.003 0.068 18.998
Σ x i= 35 151 ppm

Note that Cl makes up to 55% of salt in seawater and NaCl makes up to 86% of salt in seawater.

Example 1.5 Heat Exchanger with Feed Seawater

An adiabatic heat exchanger provides thermal load to feed seawater, such that feed seawater can be supplied to MEE desalination system at 70 °C.

Steam stream: 1 kg/s, 120 °C

State 1: saturated vapor

State 2: saturated liquid

Feed seawater stream:

State 3: 20 °C

State 4: 70 °C

x f= 40 000 ppm

Find 1 Feed seawater flow rate 2 Assume feed is fresh water find feed flow - фото 16

Find:

1 Feed seawater flow rate.

2 Assume feed is fresh water, find feed flow rate.

3 If steam (thermal load) is generated by conventional boiler using natural gas as a fuel, find fuel flow rate and emitted amount of CO2.

4 Provide emission table for three types of fuels to generate steam (thermal load).

Solution

1 Energy balance (first law): of thermal load (≈11 time of steam flow rate).Alternative solutioncp is calculated at then kg) of thermal load.

2 If feed is fresh water

3 The of natural gas fuel.For CO2 emission

4 Environmental impact of burning fossil fuels.

Fuel Calorific value (MJ/kg) CO 2(kg/kg fuel) CO 2/energy (kg/MJ) SO 2(kg/kg fuel)
Coal 26 2.361 0.091 0.018
Fuel oil 42 3.153 0.075 0.040
Natural gas 55 2.750 0.050 0

Extra activity:

Student can perform the following:

1 Perform parametric study to investigate the effect of on . Plot and explain.

2 Perform parametric study to investigate the effect of xf on . Plot and explain.

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