Encyclopedia of Glass Science, Technology, History, and Culture

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A comprehensive and up-to-date encyclopedia to the fabrication, nature, properties, uses, and history of glass
 
The
has been designed to satisfy the needs and curiosity of a broad audience interested in the most varied aspects of material that is as old as the universe. As described in over 100 chapters and illustrated with 1100 figures, the practical importance of glass has increased over the ages since it was first man-made four millennia ago. The old-age glass vessels and window and stained glass now coexist with new high-tech products that include for example optical fibers, thin films, metallic, bioactive and hybrid organic-inorganic glasses, amorphous ices or all-solid-state batteries. 
In the form of scholarly introductions, the Encyclopedia chapters have been written by 151 noted experts working in 23 countries. They present at a consistent level and in a self-consistent manner these industrial, technological, scientific, historical and cultural aspects. Addressing the most recent fundamental advances in glass science and technology, as well as rapidly developing topics such as extra-terrestrial or biogenic glasses, this important guide:
Begins with industrial glassmaking Turns to glass structure and to physical, transport and chemical properties Deals with interactions with light, inorganic glass families and organically related glasses Considers a variety of environmental and energy issues And concludes with a long section on the history of glass as a material from Prehistory to modern glass science The
has been written not only for glass scientists and engineers in academia and industry, but also for material scientists as well as for art and industry historians. It represents a must-have, comprehensive guide to the myriad aspects this truly outstanding state of matter.

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91 Chapter 9.3Figure 1 Classification of man‐made vitreous wool used for insulation. AES, ...Figure 2 Sketch of the two main techniques for forming mineral wool. (a) Cas...Figure 3 Viscosity–temperature relationships of stone and glass wool melts i...Figure 4 Phase transformations of a stone wool composition as observed in a ...Figure 5 Enthalpy relaxation of stone and glass wool samples determined in D...Figure 6 Effect of fiber diameter (as d −1) on mechanical properties o...Figure 7 Increases of tensile strength σ tswith the axial drawing stres...Figure 8 Effect of pH and chemical composition on the dissolution rate of gl...

92 Chapter 9.4Figure 1 Low‐iron glasses in photovoltaic cells. Left: first‐generation Si m...Figure 2 Spectral transmittance and loss of photon flux of different float g...Figure 3 Glass transition temperature T gof glasses used in solar‐energy con...Figure 4 Solar water heaters. Left: rooftop receiver with in‐house boiler an...Figure 5 Spectral transmittance and solar‐energy loss of 4 mm‐thick low‐iron...

93 Chapter 9.5Figure 1 Comparison between the structure of thin‐film (a) bulk‐type (b) all...Figure 2 Relationship between the electrical conductivity and the microstruc...Figure 3 Sketch of three procedures used to ensure favorable electrode–elect...Figure 4 Initial charge–discharge curves of all‐solid‐state In/LiCoO 2cells ...Figure 5 Charge–discharge curves of all‐solid‐state Li‐In/S and In/Li 2S cell...

94 Chapter 9.6Figure 1 Float lines in Europe, North America, and Middle East/Africa (from ...Figure 2 Increases of the number of float lines in Europe, North America, an...Figure 3 Float lines as of early 2013.Figure 4 Decrease of the price of clear flat glass in Western Europe from 19...Figure 5 Divergence between the prices of flat glass in Western Europe and i...

95 Chapter 9.7Figure 1 Regenerative fired furnaces for container glass. (a) End‐fired, sta...Figure 2 Specimens of other types of furnaces. (a) Recuperative furnace for ...Figure 3 Sketch of a dam wall in the melter of a glass furnace.Figure 4 A view over a wool‐glass bath through the peep hole of the melter....Figure 5 The two nozzle of gas burners (a) and the resulting gas flow (b)....Figure 6 Individual components of an end‐fired regenerative furnace.A. Reg ...Figure 7 Energy consumption as a function of specific load (t/d.m 2) used to ...Figure 8 Interplay of factors involved in NO xand SO xemissions.Figure 9 Evolutions of overall energy efficiency and emissions of NO x, SO x, ...

96 Chapter 9.8Figure 1 Fundamental parameters controlling a furnace in its dual functions ...Figure 2 Heat balance of a fuel‐fired furnace equipped with a flue‐gas heat‐...Figure 3 Efficiency of a glass furnace as a function of the heat capacity‐fl...Figure 4 Model of radiative heat exchange between combustion and melting spa...Figure 5 The influence of the pull rate, p , on the operation of a glass furn...Figure 6 Mass input–output characteristics of chemical reactors. (a) Ideal m...Figure 7 Experimental data of F ( z ) (symbols) presented in a plot W = ln[−ln(...Figure 8 Comparison between tracer residence times in a double‐convection fu...Figure 9 Comparison between calculated and measured temperature profiles for...Figure 10 Simplified picture of the glass convection flow within a melter.Figure 11 Temperature profiles and melt flow pattern in a flat‐glass furnace...Figure 12 Complete modern furnace simulation model of an end‐port, container...

97 Chapter 9.9Figure 1 Hierarchy for glass waste.Figure 2 Estimation of waste glass generated by municipal solid waste.Figure 3 Cullet treatment process. CSP, rejects of ceramic, stones, and porc...Figure 4 Mixed glass cullet.Figure 5 Sketch of a typical sorting machine for cullet.

98 Chapter 9.10Figure 1 Sketch of an incineration plant from waste delivery to incineration...Figure 2 The heterogeneous nature of bottom ash. (a) As seen with the eye. (...Figure 3 A scrap glass fragment of bottom ash shown in a backscattered scann...Figure 4 Transparent glass with yellow and brown schlieren . In the dark part...Figure 5 Crystallization of oxides and pyroxene along the dark schlieren in ...Figure 6 The heterogeneity of fly ash as seen in a backscattering electron i...

99 Chapter 9.11Figure 1 Operation of industrial vitrification plants around the world.Figure 2 Pd–Te (spherical) and RuO 2(needle‐shaped) metallic precipitates un...Figure 3 Partially crystallized beads enriched in molybdenum, phosphorus, an...Figure 4 Summary of the distinct stages of nuclear glass corrosion and relat...Figure 5 Two‐step vitrification process of nuclear waste with either “cold” ...Figure 6 Sketch of an LFCM liquid‐fed ceramic melter equipped with a bottom ...

100 Chapter 9.12Figure 1 The formal atmosphere of a meeting of glass scientist in 1928 in Aa...Figure 2 The 1967 (a) and 1994 (b) ICG logos.Figure 3 The 2010 ICG symbol.

101 Section XFigure 1 Through 25 centuries of glassmaking, an art travel at the Glasmuseu...Figure 2 Ingots of Roman glasses similar to those known by Pliny as conserve...

102 Chapter 10.1Figure 1 World map of obsidian sources utilized in ancient times. In the wes...Figure 2 Balata dei Turchi (southern side of Pantelleria, Italy) primary obs...Figure 3 Obsidian blocks (up to 40 cm in length), cores (up to 15 cm), blade...Figure 4 An obsidian sample sitting on a portable XRF instrument for the des...Figure 5 Trace element graph distinguishing Mediterranean obsidian sources....Figure 6 Multiple flows (subsources) may be distinguished on the islands of ...Figure 7 Bar chart showing source frequencies for Early Neolithic (a) and La...Figure 8 Sites with 10 or more artifacts tested (circles by the author, squa...

103 Chapter 10.2Figure 1 Blue glass lump from Eridu, believed to date to the late third mill...Figure 2 Heart amulet, Egyptian 18th Dynasty, late fourteenth century BCE (2...Figure 3 Inlay, Egyptian from Thebes, 18th dynasty (33 × 26 cm, British Muse...Figure 4 (a) Egypt (cosmetic jug, 18th dynasty, 24 × 30 cm; British Museum 2...Figure 5 The clear distinction between glasses found (and therefore thought ...Figure 6 The higher resolution of isotopic analyses: distinguishing glass ma...

104 Chapter 10.3Figure 1 Array of excavated floors of tank furnaces at Bet Eli'ezer, near Ha...Figure 2 Model for Roman glass production as currently understood. Egyptian ...Figure 3 Main compositional groups of the first millennium CE as determined ...Figure 4 The Lycurgus Cup (fourth c. CE) depicting the myth of King Lycurgus...Figure 5 Mosaic‐footed glass bowl, Victoria and Albert Museum 969–1868. Made...Figure 6 A range of forms displayed by a selected group of blown Roman‐glass...Figure 7 Typical mixing line between Roman antimony‐decolorized glass, with ...

105 Chapter 10.4Figure 1 Head of an Egyptian priest made of vitreous material (c. seventh ce...Figure 2 Oil lamp with the illustration of an artisan blowing glass in a pip...Figure 3 Pharmaceutical and chemical (?) glassware found in the Casa del Fab...Figure 4 Garden of Eden mosaic decorating the vault of the Galla Placidia Ma...Figure 5 Glass alchemical alembics illustrating the Codex Parisinus 2327 thi...

106 Chapter 10.5Figure 1 Viscosity ranges for glassworking operations and viscosity–temperat...Figure 2 Gathering of 1–3 g mosaic glass florets (slices) on a blowpipe: fin...Figure 3 Rotary scratches on the interior of a ribbed bowl fragment (Frankfu...Figure 4 Rotary scratches exhibiting horseshoe chattermarks so much shortene...Figure 5 Core‐forming furnace open at the top (height 52 cm) as designed and...Figure 6 Rotary pressing: gob of hot glass pressed with a moist wooden plung...Figure 7 Making of a ribbed bowl: sagging or flowing down of hot glass over ...Figure 8 Making of spiral reticella vessel: drawing of the thread from a rot...Figure 9 Making a Cretan pyxis : cylindrical plunger pressed into a gob of ho...Figure 10 Making of a bulbous colorband bottle: preheated colorband disk or ...Figure 11 Fragments of inflated tubes from a first century BCE Jerusalem wor...Figure 12 Pontil attachment on a newly blown glass.Figure 13 Replica of five‐part mold for a beaker, showing mythological scene...Figure 14 Mold blowing: loading of the parison in the sooted, five‐part mold...Figure 15 The basketry pattern of a cylindrical jug (height 21 cm). Syro‐Pal...Figure 16 Hellenistic sandwich gold glass bowl (height 10.7 cm, rim diameter...Figure 17 Three‐step making of gold glass : pressing of the gob of the outer ...Figure 18 Cameo glass: the Portland vase (height 24.5 cm, maximum body diame...Figure 19 Two step‐making of a cameo glass: model of wax or clay serving for...Figure 20 Diatrete, Cage cup (preserved height 12.1 cm, rim diameter 10.1 cm...Figure 21 Four‐step making of a double‐walled blank for subsequent cutting o...

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