Polar Organometallic Reagents

9 Chapter 9Scheme 9.1 Synthesis of 1‐aryl‐propenyl copper compounds with N ‐coordination...Scheme 9.2 Synthesis of a mixed alkenyl–aryl copper complex.Scheme 9.3 Synthesis of an alkenylcopper–alkyne π ‐complex.Scheme 9.4 Syntheses of mononuclear alkenylcopper–carbene complex.Scheme 9.5 Syntheses of dinuclear alkenylcopper–carbene complexes.Scheme 9.6 Revised mechanism of hydroalkylation of alkynes involving a dicop...Scheme 9.7 Syntheses and transformations of butadienyl and octatetraenyl cop...Scheme 9.8 Reaction of butadienyl 1,4‐dicopper tetramer and octatetraenyl tr...Scheme 9.9 Syntheses of styrenyl and butadienyl copper aggregates from zirco...Scheme 9.10 Formation of aromatic dicupra[10]annulenes.Scheme 9.11 Proposed mechanism for the formation of dicupra[10]annulenes.Scheme 9.12 Syntheses of spiro organocopper(I) compounds and organocopper(II...Scheme 9.13 Reductive elimination of tetra‐carbon‐linked copper(III) complex...Scheme 9.14 Synthesis and oxidation of a butadienyl spiro copper complex.Scheme 9.15 Proposed mechanism of the formation of octatetraenyl copper aggr...Scheme 9.16 Syntheses of rigid magnesium organocuprates and organoargentates...Scheme 9.17 Transformation and preliminary reactivity of magnesium organocup...

1 Cover Page

2 Title Page

3 Copyright Page

4 Preface

5 List of Contributors

6 Acknowledgements

7 Table of Contents

8 Begin Reading

9 Index

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Edited by

Andrew E. H. Wheatley

University of Cambridge

Cambridge, UK

Masanobu Uchiyama

The University of Tokyo

Tokyo, Japan

This edition first published 2022

© 2022 John Wiley & Sons Ltd

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.

The right of Andrew E. H. Wheatley and Masanobu Uchiyama to be identified as author(s) of the editorial material in this work has been asserted in accordance with law.

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