Handbook of Aggregation-Induced Emission, Volume 2

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The second volume of the ultimate reference on the science and applications of aggregation-induced emission  The Handbook of Aggregation-Induced Emission In 
, the editors address the design and synthesis of typical AIEgens that have made significant contributions to aggregation-induced emission research. Recent advances in the development of aggregation-induced emission systems are discussed and the book covers novel aggregation-induced emission systems in small molecule organogels, polymersomes, metal-organic coordination complexes and metal nanoclusters. Readers will also discover: 
A thorough introduction to the synthesis and applications of tetraphenylpyrazine-based AIEgens, AIEgens based on 9,10-distyrylanthracene , and the Salicylaldehyde Schiff base Practical discussions of aggregation-induced emission from the sixth main group and fluorescence detection of dynamic aggregation processes using AIEgens Coverage of cyclic triimidazole derivatives and the synthesis of multi-phenyl-substituted pyrrole based materials and their applications Perfect for academic researchers working on aggregation-induced emission, this set of volumes is also ideal for professionals and students in the fields of photophysics, photochemistry, materials science, optoelectronic materials, synthetic organic chemistry, macromolecular chemistry, polymer science, and biological sciences.

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Leijing LiuState Key Laboratory for Supramolecular Structure and Materials Jilin University, Changchun Jilin, China

Yali LiuState Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation‐Induced Emission South China University of Technology Guangzhou, China

Elena LucentiInstitute of Sciences and Chemical Technologies “Giulio Natta” (SCITEC) of CNR Milan, Italy

Xiang MaKey Laboratory for Advanced Materials and Institute of Fine Chemicals East China University of Science & Technology Shanghai, China

Niranjan MeherDepartment of Chemistry Indian Institute of Technology Guwahati, Guwahati, Assam, India

Vishal G. MoreSchool of Chemical Sciences Goa University, Taleigao Plateau Goa, India

Andrea PrevitaliDepartment of Chemistry Università degli Studi di Milano Milan, Italy

Anjun QinState Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation‐Induced Emission South China University of Technology Guangzhou, China

T. P. RadhakrishnanSchool of Chemistry University of Hyderabad Hyderabad, India

Bibhisan RoyFaculty of Chemistry (Organic Chemistry) University of Duisburg‐Essen Essen, Germany

Xueliang ShiShanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University Shanghai, P. R. China

N. SenthilnathanSchool of Chemistry University of Hyderabad Hyderabad, India

Siyu SunKey Laboratory for Advanced Materials and Institute of Fine Chemicals East China University of Science & Technology Shanghai, China

Kazuo TanakaDepartment of Polymer Chemistry Graduate School of Engineering Kyoto University Katsura, Kyoto, Japan

Ben Zhong TangState Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates Center for Aggregation‐Induced Emission South China University of Technology Guangzhou, China Shenzhen Institute of Aggregate Science and Technology School of Science and Engineering The Chinese University of Hong Kong Shenzhen Guangdong, China Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction The Hong Kong University of Science & Technology Clear Water Bay, Kowloon Hong Kong, China

Wenjing TianState Key Laboratory for Supramolecular Structure and Materials Jilin University, Changchun Jilin, China

Aijun TongDepartment of Chemistry Tsinghua University Beijing, China

Jens VoskuhlFaculty of Chemistry (Organic Chemistry) University of Duisburg‐Essen Essen, Germany

Zhennan WuDepartment of Chemical and Biomolecular Engineering National University of Singapore Singapore, Singapore

Jianping XieDepartment of Chemical and Biomolecular Engineering National University of Singapore Singapore, Singapore

Bin XuState Key Laboratory for Supramolecular Structure and Materials Jilin University, Changchun Jilin, China

Xuzhou YanSchool of Chemistry and Chemical Engineering Frontiers Science Center for Transformative Molecules Shanghai Jiao Tong University Shanghai, China

Hai‐Bo YangShanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University, Shanghai, China

Qiaofeng YaoDepartment of Chemical and Biomolecular Engineering National University of Singapore Singapore, Singapore

Shuang‐Quan ZangHenan Key Laboratory of Crystalline Molecular Functional Materials Henan International Joint Laboratory of Tumor Theranostical Cluster Materials Green Catalysis Center College of Chemistry, Zhengzhou University Zhengzhou, China

Yue ZhengDepartment of Chemistry Tsinghua University Beijing, China

Preface to Handbook of Aggregation‐Induced Emission

Aggregation‐induced emission (AIE) describes a photophysical phenomenon in which molecular aggregate exhibits stronger emission than its single‐molecule counterpart. AIE research provides an excellent platform to explore aggregate behaviours since it emphasizes the new properties endowed by molecular aggregates beyond the microscopic molecular level. The 21‐year development of AIE research has witnessed the great achievements in this area, including mechanistic understanding, structure‐property relationship, and high‐tech applications. The achievements of AIE research demonstrate that many behaviours and functions that are absent in molecular species can be founded in molecular aggregates. Since the properties of molecular ensembles are closer to those of macroscopic materials, AIE research is of both scientific value and technological importance for real applications.

Due to its great value and huge potential, AIE research is attracting more and more attention from chemistry, physics, materials science, medical and biomedical science and shows promising applications in these fields. Noteworthy, as a general platform to study aggregate science, AIE keeps integrating with other research fields involving materials, biology, medicine, energy and environment, and injects new vitality into these fields. When more researchers are working on this field, more breakthroughs in both fundamental research and application are envisioned in the future.

This handbook is an essential reading for scientists and engineers who are designing optoelectronic materials and chemical/biomedical sensors. It is also a valuable reference book to academic researchers in materials science, physical and synthetic organic chemistry as well as physicists and biological chemists.

Preface to Volume 2: Typical AIEgens Design

This Volume highlighted the recent advances in the development of various aggregation‐induced emission (AIE) systems, including traditional tetraphenylethenes based, 9,10‐distyrylanthracene based, salicylaldehyde Schiff based, and multi‐phenyl‐substituted pyrrole based AIE systems, and systems with extended π‐conjugations to those even without typical AIE chromophores. Meanwhile, novel AIE systems in small molecule organogels, polymersomes, metal‐organic coordination complexes, metal nanoclusters and others are demonstrated in this volume. The fluorescent behaviours of these AIE system toward different application are also explored.

Youhong Tang, Flinders University, Australia

Ben Zhong Tang, The Chinese University of Hong Kong, Shenzhen, China

1 Tetraphenylpyrazine‐based AIEgens: Synthesis and Applications

Ming Chen1, Anjun Qin3, and Ben Zhong Tang2,3,4

1College of Chemistry and Materials Science, Jinan University, Guangzhou, China

2Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China

3State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation‐Induced Emission, South China University of Technology, Guangzhou, China

4Shenzhen Institute of Aggregate Science and Technology, School of Science and Engineering, The Chinese University of Hong Kong, Shenzhen, Guangdong, China

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