Surya K. De - Applied Organic Chemistry

Applied Organic Chemistry — читать онлайн ознакомительный отрывок

Ниже представлен текст книги, разбитый по страницам. Система сохранения места последней прочитанной страницы, позволяет с удобством читать онлайн бесплатно книгу «Applied Organic Chemistry», без необходимости каждый раз заново искать на чём Вы остановились. Поставьте закладку, и сможете в любой момент перейти на страницу, на которой закончили чтение.

Тёмная тема

Шрифт:

↓

↑

Georgia Georgia Tahoma Arial Verdana Symbol

Сбросить

Интервал:

↓

↑

Закладка:

Сделать

1 ...2 3 4 5 6

»

8 9

Acknowledgments

The author would like to extend his gratitude to the original publishers for experimental procedures for granting permission to use in this book. The publishers include the American Chemical Society, Elsevier, the Royal Society of Chemistry, John Wiley & Sons, Wiley VCH‐Verlag, Thieme, and the Japan Institute of Heterocyclic Chemistry. I would like to thank all inventors for patent literatures cited in this book.

List of Abbreviations

Abbreviation	Name	Chemical structure
Å	Ångström	NA
Ac	Acetyl
Acac	Acetylacetonyl
AIBN	2,2′‐Azobisisobutyronitrile
Alloc	Allyloxycarbonyl
Aq	Aqueous	With water
Ar	Aryl	Substituted aromatic ring
9‐BBN	9‐Borabicyclo[3.3.1]nonane
BINAL‐H	2,2′‐Dihydroxy‐1,1′‐binaphthyl lithium aluminum hydride
BINAP	2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl
BINOL	1,1′‐Bi‐2,2′‐naphthol
BMS	Borane dimethyl sulfide complex	H 3B • SMe 2

Abbreviation	Name	Chemical structure
Boc	tert ‐Butoxycarbonyl
BOM	Benzyloxymethyl
b.p.	Boiling point	NA
BPO	Benzoyl peroxide
Bn	Benzyl
br	Broad	NA
Bz	Benzoyl
n ‐Bu	n ‐Butyl
t ‐Bu	tert ‐Butyl
°C	Degree Celsius	NA
13C NMR	Carbon NMR	NA
CAN	Ceric ammonium nitrate	(NH 4) 2Ce(NO 3) 6
cat.	Catalytic	NA
Cbz (Z)	Benzyloxycarbonyl
conc.	Concentrated	NA
COSY	Correlation spectroscopy	NA
CDI	Carbonyldiimidazole
CSA	Camphorsulfonic acid
CTAB	Cetyltrimethylammonium bromide
Δ	Chemical shift in ppm	NA
d	Doublet	NA
DABCO	1,4‐Diazabicyclo[2.2.2]octane

Abbreviation	Name	Chemical structure
DAST	Diethylaminosulfur trifluoride
Dba	Dibenzylideneacetone
DBAD	Di‐ tert ‐butyl azodicarboxylate
DBU	1,8‐Diazabicyclo[5.4.0]undec‐7‐ene
DCC	N,N′ ‐Dicyclohexylcarbodiimide
DCE	1,2‐Dichloroethane
DCM	Dichloromethane	CH 2Cl 2
DCU	N,N′ ‐Dicyclohexylurea
DDQ	2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone
de	Diastereomeric excess	NA
DEAD	Diethyl azodicarboxylate
DET	Diethyl tartrate
DHP	3,4‐Dihydro‐2H‐pyran
(DHQ) 2PHAL	Bis(dihydroquinino)phthalazine

Abbreviation	Name	Chemical structure
(DHQD) 2‐PHAL	Bis(dihydroquinidino)phthalazine
DIAD	Diisopropyl azodicarboxylate
DAIB (DIB)	(Diacetoxyiodo)benzene
DIBAL‐H	Diisobutylaluminum hydride
DIC	Diisopropylcarbodiimide
DIEA (DIPEA)	Diisopropylethylamine
DIPT	Diisopropyl tartrate
DMA	N,N ‐Dimethylacetamide
DMAP	4‐ N,N ‐Dimethylaminopyridine
DME	1,2‐Dimethoxyethane
DMF	N,N ‐Dimethylformamide
DMP	Dess–Martin periodinane

Abbreviation	Name	Chemical structure
DMPS	Dimethylphenylsilyl
DMS	Dimethyl sulfide
DMSO	Dimethyl sulfoxide
DPPA	Diphenylphosphoryl azide
DPS (TBDPS)	tert ‐Butyldiphenylsilyl
DTT (DTE)	1,4‐Dithioerythritol
E1	Unimolecular elimination	NA
E2	Bimolecular elimination	NA
EDC (EDCI)	1‐Ethyl‐3‐(3‐dimethylaminopropyl)carbodiimide
EDG	Electron‐donating group	NA
EDTA	Ethylenediaminetetraacetic acid
ee	Enantiomeric excess	NA
E i	Intramolecular syn elimination	NA
Et	Ethyl
Equiv.	Equivalent	NA
EWG	Electron‐withdrawing group	NA
Fmoc	9‐Fluorenylmethoxycarbonyl
Fp	Flash point	NA
g	Grams	NA
GC	Gas chromatography	NA
h	Hour	NA

Abbreviation	Name	Chemical structure
HATU	O‐(7‐Azabenzotriazol‐1‐yl)‐N,N,N′,N′‐tetramethyluronium hexafluorophosphate
HBTU	Hexafluorophosphate Benzotriazole Tetramethyl Uronium
HFIP	1,1,1,3,3,3‐Hexafluoro‐2‐propanol (hexafluoroisopropanol)
HMDS	1,1,1,3,3,3‐Hexamethyldisilazane
HMPA	Hexamethylphosphoric acid triamide (hexamethylphosphoramide)
HMPT	Hexamethylphosphorous triamide
HOAt	1‐Hydroxy‐7‐azabenzotriazole
HOBt	1‐Hydroxybenzotriazole
HOMO	Highest occupied molecular orbital	NA
HPLC	High‐performance liquid chromatography	NA
HTIB	[Hydroxy(tosyloxy)iodo]benzene
Hz	Hertz	NA
1H NMR	Proton NMR	NA
HMBC	Heteronuclear multiple bond coherence	NA

Abbreviation	Name	Chemical structure
HSQC	Heteronuclear single quantum coherence	NA
IBX	o ‐Iodoxybenzoic acid
IPA	Isopropyl alcohol
IR	Infrared spectroscopy	NA
J	Coupling constant	NA
KHMDS	Potassium bis(trimethylsilyl)amide
L	Ligand	NA
LAH	Lithium aluminum hydride	LiAlH 4
LHMDS (LiHMDS)	Lithium bis(trimethylsilyl)amide
Liq.	Liquid	NA
LiTMP (LTMP)	Lithium 2,2,6,6‐tetramethylpiperidide
L.R.	Lawesson's reagent 2,4‐Bis(4‐methoxyphenyl)‐1,3,2,4‐dithiadiphos‐phetane‐2,4‐disulfide
L‐selectride	Lithium tri‐sec‐butylborohydride
LTA	Lead tetraacetate	Pb(OAc) 4
LUMO	Lowest unoccupied molecular orbital	NA
Lut	2,6‐Lutidine
m	Meta	NA
m	Multiplet	NA

Abbreviation	Name	Chemical structure
M	Moles/liter	NA
m ‐CPBA	meta‐Chloroperbenzoic acid
Me	Methyl	−−CH 3
MEM	(2‐Methoxyethoxy)methyl
MIC	Methyl isocyanate
min	Minute	NA
mg	Milligrams	NA
ml	Milliliters	NA
Mol	Moles	NA
mmol	Millimoles	NA
μl	Microliters	NA
MOM	Methoxymethyl
m.p.	Melting point	NA
Ms	Mesyl (methanesulfonyl)
MS	Mass spectrometry	NA
MS	Molecular sieves	NA
MSA	Methanesulfonic acid
MSDS	Material safety data sheet	NA
MTBE	Methyl ter t‐butyl ether
MVK	Methyl vinyl ketone
Mv	Microwave	NA
n	Normal (e.g. unbranched alkyl chain)	NA
NaHMDS	Sodium bis(trimethylsilyl)amide Sodium hexamethyldisilazane
NBS	N ‐Bromosuccinimide

Abbreviation	Name	Chemical structure
NCS	N ‐Chlorosuccinimide
NIS	N ‐Iodosuccinimide
NMM	N ‐Methylmorpholine
NMO	N ‐Methylmorpholine oxide
NMP	N ‐Methyl‐2‐pyrrolidinone
NMR	Nuclear magnetic resonance	NA
NSAID	Nonsteroidal anti‐inflammatory drug	NA
Nuc/Nu	Nucleophile	NA
o	Ortho	NA
p	Para	NA
Pbf	2,2,4,6,7‐Pentamethyldihydrobenzofuran‐5‐sulfonyl
31P NMR	Phosphorus NMR	NA
PBP	Pyridinium bromide perbromide
PCC	Pyridinium chlorochromate
PDC	Pyridinium dichromate

Abbreviation	Name	Chemical structure
Pd 2(dba) 3	Tris(dibenzylideneacetone)dipalladium
Pd(dppf)Cl 2	[1,1′‐Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
PdCl 2(PPh 3) 2	Bis(triphenylphosphine)palladium(II) dichloride
Pd(PPh 3) 4	Tetrakis(triphenylphosphine)palladium(0)	(Ph 3P) 4Pd
PhI(OH)OTs	[Hydroxyl(tosyloxy)iodo]benzene
PEG	Polyethylene glycol
Ph	Phenyl
PHAL	Phthalazine
PIFA	Phenyliodonium bis(trifluoroacetate)
Piv	Pivaloyl
PMB	p ‐Methoxybenzyl
PMP	4‐Methoxyphenyl

Abbreviation	Name	Chemical structure
PNB	p ‐Nitrobenzyl
ppm	Parts per million	NA
PPTS	Pyridinium p ‐toluenesulfonate
Pr	Propyl
P.T.	Proton transfer	NA
PTAB	Phenyltrimethylammonium perbromide
PTSA (TsOH)	p ‐Toluenesulfonic acid
r.t. (rt)	Room temperature	NA
R f	Retention factor in chromatography	NA
ROM	Ring‐opening metathesis	NA
ROMP	Ring‐opening metathesis polymerization	NA
RB (Rose Bengal)	2,4,5,7‐Tetraiodo‐3′,4′,5′,6′‐tetrachlorofluorescein, disodium salt (a photosensitizer, dye)
s	Singlet	NA
SDS	Sodium dodecyl sulfate
Selectfluor	N ‐Chloromethyl‐ N ′‐fluorotriethylenediammonium bis(tetrafluoroborate)
SEM	2‐(Trimethylsilyl)ethoxymethyl
SET	Single‐electron transfer	NA
S NAr	Nucleophilic substitution on an aromatic ring	NA

Abbreviation	Name	Chemical structure
S N1	Unimolecular nucleophilic substitution	NA
S N2	Bimolecular nucleophilic substitution	NA
SPB	Sodium perborate	NaBO 3
t	Triplet	NA
TBAB	Tetra‐ n ‐butylammonium bromide
TBAF	Tetra‐ n ‐butylammonium fluoride
TBAI	Tetra‐ n ‐butylammonium iodide
TBD	Triazabicyclodecene (1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene
TBDMS (TBS)	tert ‐Butyldimethylsilyl
TBDPS (BPS)	tert ‐Butyldiphenylsilyl
TBH	tert ‐Butyl hypochlorite
TBHP	tert ‐Butyl hydroperoxide
TBP	Tributylphosphine
TBTH	Tributyltin hydride

Abbreviation	Name	Chemical structure
TBTSP	tert ‐Butyl trimethylsilyl peroxide
TCCA	Trichloroisocyanuric acid
TCDI	Thiocarbonyldiimidazole
TCNE	Tetracyanoethylene
TCNQ	7,7,8,8‐Tetracyano‐ para ‐quinodimethane
TEA	Triethylamine
TEMPO	2,2,6,6‐Tetramethyl‐1‐piperidinyloxy free radical
Teoc	2‐(Trimethylsilyl)ethoxycarbonyl
TEP	Triethylphosphite
TES	Triethylsilyl
Tf	Trifluoromethanesulfonyl
TFA	Trifluoroacetic acid
TFAA	Trifluoroacetic anhydride
TFE	2,2,2‐Trifluoroethanol
TFMSA	Trifluoromethanesulfonic acid (triflic acid)

Abbreviation	Name	Chemical structure
THF	Tetrahydrofuran
THP	2‐Tetrahydropyranyl
TIPS	Triisopropylsilyl
TIPS	Triisopropylsilane
TMP	2,2,6,6‐Tetramethylpiperidine
TMS	Trimethylsilyl
TMSA	Trimethylsilyl azide
TMU	Tetramethylurea
TPAP	Tetra‐ n ‐propylammonium perruthenate
TPP	Triphenylphosphine
TPS	Triphenylsilane
Trt	Trityl (triphenylmethyl)

Abbreviation	Name	Chemical structure
T.S.	Transition state	NA
Ts (Tos)	p ‐Toluenesulfonyl
TTN	Thallium(III) trinitrate	Tl(NO 3) 3
UHP	Urea–hydrogen peroxide complex
Z (Cbz)	Benzyloxycarbonyl

Polarity of Solvents

Читать дальше

1 ...2 3 4 5 6

»

8 9

Тёмная тема

Шрифт:

↓

↑

Georgia Georgia Tahoma Arial Verdana Symbol

Сбросить

Интервал:

↓

↑

Закладка:

Сделать

Похожие книги на «Applied Organic Chemistry»

Представляем Вашему вниманию похожие книги на «Applied Organic Chemistry» списком для выбора. Мы отобрали схожую по названию и смыслу литературу в надежде предоставить читателям больше вариантов отыскать новые, интересные, ещё непрочитанные произведения.

Ron Rash

Chemistry and Other Stories

Peter Carey

The Chemistry of Tears

Неизвестный Автор

Reviews in Computational Chemistry, Volume 32

Dennis D. Miller

Food Chemistry

Cheanyeh Cheng

Enzyme-Based Organic Synthesis

Неизвестный Автор

Organic Corrosion Inhibitors

Iain Pardoe

Applied Regression Modeling

Richard M. Pashley

Applied Colloid and Surface Chemistry

Неизвестный Автор

Applied Water Science

Неизвестный Автор

Applied Soil Chemistry

Gary A. Mabbott

Electroanalytical Chemistry

Herbert Spencer

The Factors of Organic Evolution

Обсуждение, отзывы о книге «Applied Organic Chemistry» и просто собственные мнения читателей. Оставьте ваши комментарии, напишите, что Вы думаете о произведении, его смысле или главных героях. Укажите что конкретно понравилось, а что нет, и почему Вы так считаете.