Handbook of Aggregation-Induced Emission, Volume 2

12 Chapter 12Figure 12.1 Two strategies to construct the classical fluorescent polymersom...Figure 12.2 Comparison between fluorescent polymersomes with (a) ACQ and (b)...Figure 12.3 Different self‐assembled nanostructures formed from amphiphilic ...Figure 12.4 (a) Synthetic route to PEG‐ b ‐POSS(TPE) 7. (b) TEM images and (c) ...Figure 12.5 (a) Synthetic route to P(TPE‐NAG)‐ b ‐PSar. (b) Cryo‐EM images of ...Figure 12.6 (a) Synthetic route to PEG 45‐ b ‐P(TPE‐TMC) n. (b–e) Cryo‐EM images...Figure 12.7 (a) Evolution of hydrodynamic diameter D hand count rates of pol...Figure 12.8 (a) Synthetic route to poly( M 1)‐ b ‐poly( M 2). (b–d) TEM image of n...Figure 12.9 Preparation of poly( M 2)‐ b ‐poly( M 1‐ co ‐ M 3) block copolymers and th...Figure 12.10 (a) Synthetic route to poly( N ‐DSAnthracene)‐ b ‐poly( N ‐PEG) and p...Figure 12.11 (a) Synthesis of CO 2‐responsive AIE amphiphilic block copolymer...Figure 12.12 (a) Reversible protonation and deprotonation processes of DEAEM...Figure 12.13 Schematic representation of the preparation of AIE nanostructur...Figure 12.14 Size and morphology characterization of the PDMA 39‐ b ‐P(BzMA‐TPE...Figure 12.15 (a) The synthetic route to P(HEO 2MA) 40‐ b ‐P(MAEBA x‐DMAEMA y‐TPEMAFigure 12.16 Vesicle‐forming AIE block copolymers discussed in this chapter....

13 Chapter 13Figure 13.1 Chemical structures of boron element‐blocks for constructing fun...Figure 13.2 Schematic drawing on the emission mechanism of aryl‐modified o ‐c...Figure 13.3 Chemical structures and optical properties of AIE‐active polymer...Figure 13.4 Schematic model of stimuli‐responsive emissive hydrogels contain...Figure 13.5 Luminescent spectra of anthracene‐modified o ‐carborane. Normaliz...Figure 13.6 Chemical structures of TPA‐substituted o ‐carboranes and represen...Figure 13.7 Chemical structures of o ‐carborane derivatives having highly int...Figure 13.8 Chemical structure, luminescent spectra, and plausible model for...Figure 13.9 Optical properties of boron diketonate and β‐ketiminates.Figure 13.10 Optical properties of boron ketiminates and plausible mechanism...Figure 13.11 Chemical structure of the dye‐modified POSS with thermally dura...Figure 13.12 Chemical structures and optical properties of boron β‐diketimin...Figure 13.13 Chemical structures and photophysical properties of conjugated ...Figure 13.14 Chemical structures and plausible reaction schemes of film‐type...Figure 13.15 A chemical structure and vapochromic fluorescence property of g...Figure 13.16 Chemical structures of BPIand FBPIand plausible models of the...Figure 13.17 (a) Changes in intensity ratios by the aggregation formation in...Figure 13.18 Chemical structures, optical properties, and optimized structur...Figure 13.19 Thermosalient effects of Azwith thermochromic luminescence....Figure 13.20 Chemical structures and photophysical properties of a monomer a...

14 Chapter 14Figure 14.1 The conception and design strategy of combining AIE with coordin...Figure 14.2 (a) Self‐assembly of TPE‐based ligand L1and acceptor 1into tri...Figure 14.3 (a) Self‐assembly of TPE‐based ligand L2and the 60° diplatinum(...Figure 14.4 Self‐assembly of TPE‐based ligand L4with the corresponding dipl...Figure 14.5 (a) Self‐assembly of L4with L5to give pure TPE‐based metallacy...Figure 14.6 (a) Self‐assembly of TPE‐based ligands L6–L8with Cd 2to f...Figure 14.7 (a) Syntheses of double rhomboid M15and double triangle M16via...Figure 14.8 (a) Synthesis of the dinuclear fused AIE active metallacycles M1...Figure 14.9 (a) The interaction between pyridine‐decorated TPE ligand L11an...Figure 14.10 (a) Graphical representation of the synthesis of TPE‐based orga...Figure 14.11 (a) Cartoon representation of the synthesis of AIE active metal...Figure 14.12 (a) Chemical structures of three phenanthrene‐21‐crown‐7 (P21C7...Figure 14.13 (a) Graphical representation of the self‐assembled metallacycle...Figure 14.14 (a) Synthesis of AIE active metallacages M30and M31via a mult...Figure 14.15 (a) Synthetic routes and cartoon representations of cages M32‐ Figure 14.16 (a) Formation and the X‐ray structure of M35. (b) Photoluminesc...Figure 14.17 (a) Self‐assembly of a lantern‐type Pd 2L 4capsule M36and its s...Figure 14.18 (a) Self‐assembly of exo‐ and endo‐functionalized M 12L 24nanosp...Figure 14.19 (a) Schematic showing self‐assembly of M20with NH 4+binder thr...Figure 14.20 (a) The synthesis of MOF M21and M22and their crystal structur...Figure 14.21 (a) The synthesis of MOF M23and its crystal structure and topo...Figure 14.22 (a) The synthesis of MOF M24and its crystal structure. (b) Syn...Figure 14.23 (a) The synthesis of MOF M25. (b) Optical absorption spectra of...Figure 14.24 (a) The synthesis of MOF M24and its crystal structure. (b) DFT...Figure 14.25 (a) The synthesis of MOF M25and its crystal structure viewed a...

15 Chapter 15Figure 15.1 (a) Transmission electron microscope (TEM) and scanning Transmis...Figure 15.2 (a) Digital photos of luminescent Ag NCs in water. (b) UV–vis ab...Figure 15.3 (a) The ball stick structure model of Au 22(SR) 18predicted by DF...Figure 15.4 (a) Schematic illustration of binding TOA to Au 22(SG) 18clusters...Figure 15.5 (a) Schematic illustration of the two pathways influencing the l...Figure 15.6 (a) PL emission and excitation spectra of the Ag−carboxylate NCs...Figure 15.7 (a) Schematic illustration of EtOH‐induced AIE of Cu 32‐34(...Figure 15.8 (a) Schematic illustration of AIEE‐based Ag NCs nanoswitches in ...Figure 15.9 (a) Optical microscopy image of the luminescent Au 4Ag 13(DPPM) 3(S...Figure 15.10 (a) Schematic illustration of the growth process and the struct...Figure 15.11 (a) Schematic representation of the ligand‐exchange strategy us...Figure 15.12 (a) The Au 22(SG) 18NCs were delivered into bare Moorella thermo ...

16 Chapter 16Figure 16.1 (a) Schematic illustration of solvent‐induced AIE effect of olig...Figure 16.2 The cartoon pictures illustrate the structure of (a) [Au 25(SR) 18Figure 16.3 (a) From left to right: Ultraviolet‐visible (UV‐vis) absorption ...Figure 16.4 (a) Structures of complexes. (b) Emission spectra of [Au 10(Ph 2PN...Figure 16.5 (a) The overall structures of R‐Au 3and S‐Au 3. Color...Figure 16.6 (a) Absorption/diffuse reflectance (solid lines) and emission (d...Figure 16.7 (a) Schematic illustration of solvent‐induced AIE properties of ...Figure 16.8 (a) Enhancement of photoluminescence (PL) intensity and quantum ...Figure 16.9 (a) Illustration of the synthesis of Ag 9. (b) Photos of Ag 9in a...Figure 16.10 The overall structures and superatomic orbitals of Ag 22.Figure 16.11 (a) Ball‐and‐stick representation of the enantiomers of Ag 6 L 6 /DFigure 16.12 (a) Emission spectra of the aqueous copper clusters aggregates ...Figure 16.13 (a) Schematic diagram and corresponding TEM images of copper na...Figure 16.14 Schematics of the formation and treatment of orange and blue em...Figure 16.15 Imidazole based ligands and the effect of substituents on the s...Figure 16.16 (a) Relative arrangement of [Cu 5(S tBu) 6] −in cyan polyhed...Figure 16.17 (a) The structures of R/S‐Cu 14and the metal frameworks i...Figure 16.18 (a) Synthetic route of R/S‐Cu 3. (b) Crystal structure of Figure 16.19 Illustration of the Au(0)‐induced aggregation of nonemissive co...Figure 16.20 (a) The structure of Au 4 Ag 13. Color labels: Ag, light blue; Au,...Figure 16.21 (a) Crystal structure of Au 4 Ag 5. (b) Photo of samples under vis...Figure 16.22 (a) Emission spectra and (b) the corresponding fluorescence ima...