Handbook of Aggregation-Induced Emission, Volume 3

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The third volume of the ultimate reference on the science and applications of aggregation-induced emission  The Handbook of Aggregation-Induced Emission In 
the editors address the applications of AIEgens in several fields, including bio-imaging, fluorescent molecular switches, electrochromic materials, regenerative medicine, detection of organic volatile contaminants, hydrogels, and organogels. Topics covered include: 
AIE-active emitters and their applications in OLEDs, and circularly polarized luminescence of aggregation-induced emission materials AIE polymer films for optical sensing and energy harvesting, aggregation-induced electrochemiluminescence, and mechanoluminescence materials with aggregation-induced emission Dynamic super-resolution fluorescence imaging based on photoswitchable fluorescent spiropyran Visualization of polymer microstructures Self-assembly of micelle and vesicles New strategies for biosensing and cell imaging Perfect for academic researchers working on aggregation-induced emission, this set of volumes is also ideal for professionals and students in the fields of photophysics, photochemistry, materials science, optoelectronic materials, synthetic organic chemistry, macromolecular chemistry, polymer science, and biological sciences.

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and c... Figure 2.10 Molecular structures of chiral Au 3cluster enantiomers R41and Figure 2.11 (a) Molecular structures of chiral ligands R ‐DPM and S ‐DPM. (b) ... Figure 2.12 Molecular structures of chiral copper cluster enantiomers R43a... Figure 2.13 Molecular structures of chiral silole‐based AIEgens 4447and co... Figure 2.14 Molecular structures of chiral TPE‐based AIEgens 4851and corre... Figure 2.15 Molecular structures of chiral TPE‐based AIEgens 5254and corre... Figure 2.16 Molecular structures of triangular macrocycle 55, TPE dual cycle... Figure 2.17 (a) Molecular structure of chiral AIEgen 58. (b) Scanning electr... Figure 2.18 (a) Molecular structures of R59and S59and schematic illustra... Figure 2.19 Schematic illustration of DNA‐biscyanine hybrid CPL‐active mater... Figure 2.20 Molecular structures of TPE macrocycle diquaternary ammoniums (a... Figure 2.21 (a) Schematic illustration of the co‐assembly processes. (b) Mol... Figure 2.22 Schematic illustration of the co‐assembly of molecules 66and 67 Figure 2.23 (a) Molecular structures of chiral gold complex enantiomers R68 Figure 2.24 (a) Molecular structure of chiral TPE‐containing polymer 69and ... Figure 2.25 Molecular structures of AIE‐active chiral conjugated polymers 70 Figure 2.26 Molecular structures of AIE‐active three‐component chiral conjug... Figure 2.27 (a) Molecular structures of AIE‐active chiral conjugated polymer... Figure 2.28 (a) Molecular structure of chiral conjugated polymer 84and corr... Figure 2.29 (a) Molecular structure of 85and corresponding g lum. (b) Schema... Figure 2.30 Molecular structure of achiral AIEgen 86[66]. Figure 2.31 (a) Molecular structures of R87and S87. (b) CPL spectra of N*... Figure 2.32 (a) Molecular structures of chiral dopant enantiomers R88and S

3 Chapter 3 Figure 3.1 Strategies for obtaining AIE‐doped polymer films by means of (a) ... Figure 3.2 Working principle of the AIE mechanism: nonplanar fluorophores st... Figure 3.3 Potential energy diagram for generic FMRs and the respective emis... Figure 3.4 Fluorescence spectra ( λ exc= 360 nm) of a 0.01 wt.% of the... Figure 3.5 Evaluation of damage detection in encapsulated AIE polymer coatin... Figure 3.6 Chemical structure of TPE‐4N and fluorescence intensity changes o... Figure 3.7 Fluorescence Φ Fof PS, SBS, and SBR films doped with 0.1 wt.... Figure 3.8 Chemical structure of the TPE‐functionalized PCL polymer and reve... Figure 3.9 DPAP and (a) emission band variations of 0.05 wt.% DPAP/PMMA film... Figure 3.10 Chemical structures of TPE_RED and PMMA_TPE_RED 1.5AIE‐doped pol... Figure 3.11 Working mechanism of an LSC (left) and potential application of ... Figure 3.12 Chemical structure of the PMMA_TPE_RED and photo of the derived ...

4 Chapter 4 Figure 4.1 [Ru(bpy) 3] 2+structure and its cyclic voltammetry in acetonitrile... Figure 4.2 Schematic diagram describing the electron transfer reactions resp... Figure 4.3 Schematic diagram describing the electron transfer reactions resp... Figure 4.4 (a, d) Chemical structures of the investigated complexes; (b) Pho... Figure 4.5 (a) Chemical structure of complex 3; (b)TEM analysis of nanoparti... Figure 4.6 (a) Chemical structures of polymers P1 and P2; (b) CVs (a and b) ... Figure 4.7 (a) TPE molecular structure; (b) ECL‐potential profile for bare G... Figure 4.8 (a) Molecular structure of 1,1‐disubstituted 2,3,4,5‐tetraphenyls... Figure 4.9 (a) Illustration of bivalent cations induced aggregation of NCs w... Figure 4.10 Relationship between I 0and I of AI‐ECL of DPA‐CM NPs (inset) an... Figure 4.11 (a) Illustration of AI‐ECL through self‐assembly; (b) schematic ...

5 Chapter 5Figure 5.1 Molecular packing mode of crystals with different ML properties....Figure 5.2 Proposed mechanisms for ML and photo‐in‐duced RTP processes. (a) ...Figure 5.3 The apparent state and PL images of the different colored doped s...Figure 5.4 The strategy of alkyl chain introduction: after introducing an al...Figure 5.5 (a) Stereogram (up) and cross‐section view (below) of the sandwic...Figure 5.6 Design of the guest/host system. (a) Schematic illustration of th...Figure 5.7 (a) ML spectra of 64in different phases; (b) an image of the cap...Figure 5.8 The new design of the ML material and chemical structure of 83wi...

6 Chapter 6Figure 6.1 Schematic representation of super‐resolution imaging system.Figure 6.2 (a) The fluorescence spectra change along with the 365 nm light i...Figure 6.3 The principle of super‐resolution imaging: (a) schematic of SP an...Figure 6.4 Single molecule/particle fluorescence intensity trajectories SPTS...Figure 6.5 Super‐resolution fluorescence imaging of PSt‐ b ‐PEO block copolyme...Figure 6.6 Optimization of spatial resolution for SPTS super‐resolution fluo...Figure 6.7 Time‐varying super‐resolution fluorescence imaging: (a) super‐res...Figure 6.8 Sequential nanoscale in situ optical visualization for solvent an...

7 Chapter 7Figure 7.1 (a) Chemical structures of ( Z )‐TPE‐UPy and ( E )‐TPE‐Upy. (b) Schem...Figure 7.2 (a) The polymerization process of visible light‐induced RAFT poly...Figure 7.3 (a) Schematic illustration of the working principle of the AIE te...Figure 7.4 (a) Chemical structures of polymer PMT and PVT. (b) Variation of ...Figure 7.5 (a) Synthetic route to polymer TPE‐PEG. (b–h) Real‐time fluoresce...Figure 7.6 Schematic representation of the proposed working mechanisms for t...Figure 7.7 (a) Synthetic route to TPE‐nylon‐6. Fluorescence spectra of (b) T...Figure 7.8 Humidity‐sensitive fluorescent sensors. (a) Schematic illustratio...Figure 7.9 (a) DNA synthesis detection by AIEgens through EdU assay. (b) Det...Figure 7.10 (a) A schematic illustration of the application of TPE‐2N 3for n...Figure 7.11 Strategy for assaying protein folding via access to buried cyste...Figure 7.12 Monitoring of protein fibrillation by AIE‐active TPE‐TPP and com...

8 Chapter 8Figure 8.1 Structures of various micelles and a unilamellar vesicle.Figure 8.2 (a) The molecular structures of TPE–SDS and TPE–DTAB. (b) Plot of...Figure 8.3 (a) Molecular structure of 1and schematic diagram for the format...Figure 8.4 (a) Molecular structure of 2and its self‐assembly. (b) UV/vis sp...Figure 8.5 Molecular structures of compounds 37to demonstrate incorporatin...Figure 8.6 (a) TEM image of 10with a concentration of 0.2 mg/ml. (b) PL spe...Figure 8.7 Molecular structures of amphiphilic block AIE copolymers 9and 10Figure 8.8 (a) Plots of relative intensity ( I 510/ I 450) of HBT‐C 18versus the...Figure 8.9 (a) PL spectra of HBT‐C 18(5 μM) versus SDBS concentration in aqu...Figure 8.10 (A) Chemical structures of compounds 12and 13. (B) Confocal las...Figure 8.11 Formation of AIE‐M and its FL responding to Cu 2+/S 2−[14]....Figure 8.12 The formation of AIE micelles with PEG‐Azo‐TPE polymer (a) and i...Figure 8.13 (a) Schematic illustration of DOX‐loaded self‐assembly micelle (...Figure 8.14 Time course of DOX release from TPED and cellular uptake of free...Figure 8.15 (a) The ex vivo imaging of the excised organs and tumors at diff...Figure 8.16 CLSM images of cells incubated with TSPG/DNA complexes for four ...Figure 8.17 (a–e) Luciferase expression induced by complexes at various weig...Figure 8.18 (a) FL titrations of 1with increasing Cu 2+in water at room tem...Figure 8.19 FL microscopy images of the TPE–SDS micelles in (a) pure water, ...Figure 8.20 CFM images of different stages of different concentrations of TP...Figure 8.21 Two‐dimensional (2D) FL images of algae interacting with 20 μM T...Figure 8.22 Schematic representation of the visualization of 3D macrodispers...Figure 8.23 (a) Schematic illustration of the preparation of vesicles with a...Figure 8.24 (a) Chemical structures of TPE–bile acid conjugates 1418. (b) S...Figure 8.25 (a) Chemical structure of (TCBD) 2‐OPV 3. (b) Chemical structure o...Figure 8.26 (a) Molecular structures of the host molecule WC4P and guest com...Figure 8.27 (a) Structures of TPE–BPA and CTAB. (b) Formation of vesicles wi...Figure 8.28 (a) Molecular structure of TPA‐1. (b) Illustration of the self‐a...Figure 8.29 (a) Illustration of the self‐assembly of TPE–BPA/CTAB vesicles a...Figure 8.30 (a) Molecular structure of TPEI‐C8. (b) TEM image for the vesicl...Figure 8.31 (a) Drug release profiles for 2TPA‐1@Zn 2+fluorescent vesicles a...Figure 8.32 (a) The self‐assembly of TPE–BPA@8MChCl system. (b) Enzymatic re...Figure 8.33 (a) Illustration of the self‐assembly of TPE–BPA@8CTAB vesicles,...Figure 8.34 (a) Illustration of the self‐assembly of pillar[5]arene‐based aq...

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