Johannes Karl Fink - Flame Retardants

2 Chapter 2Figure 2.1 Synthesis of a diphenolic acid-based biphosphate (11).Figure 2.2 Benzoxazine monomer with triazine structure (15).Figure 2.3 Flame retardant compounds.Figure 2.4 Synthesis of DTA (18).Figure 2.5 The synthesis of ATZ (22).

3 Chapter 3Figure 3.1 Synthesis of poly(sulfonyldiphenylene thiophenylphosphonate) (13)...Figure 3.2 Poly(2-hydroxy propylene spirocyclic pentaerythritol bisphosphona...Figure 3.3 Synthesis of a hyperbranched poly(amine) (16).Figure 3.4 Synthesis of 5-(benzylidene-amino)-isophthalic acid dimethyl este...Figure 3.5 PA6-COOH and 1,3-Bis(3-aminopropyl)tetramethyl disiloxane.Figure 3.6 Aldimine reaction (27).Figure 3.7 Synthesis of PCNFR (28).Figure 3.8 Synthesis of triglycidyl phosphate.

4 Chapter 4Figure 4.1 Smoke density ( Dmaxg −1) versus chlorine content (%) (19).Figure 4.2 Ammonium molybdophosphate.Figure 4.3 Phosphorus-containing polyol (38).Figure 4.4 Tetraethyl orthosilicate.Figure 4.5 Synthesis of monocardanyl phosphoric acid (44).Figure 4.6 Compounds for modification of nanocomposites (46).Figure 4.7 Metal-based organic complexes.

5 Chapter 5Figure 5.1 Tested flame retardants.Figure 5.2 Other flame retardants.

6 Chapter 6Figure 6.1 Tetrabromobisphenol A.

7 Chapter 7Figure 7.1 Pentabromobenzyl acrylate.Figure 7.2 Condensation of 1,2,6-Tribromophenol.Figure 7.3 Phosphine oxides.Figure 7.4 Bis(glycidyloxy)phenyl phosphine oxide.Figure 7.5 Diaminophenyl commpounds.Figure 7.6 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.Figure 7.7 Phosphorylation of poly(4-hydroxystyrene) (51).Figure 7.8 Phosphor-containing monomers (47).Figure 7.9 Spirocyclic pentaerythritol di(phosphoric acid monochloride) (56)...Figure 7.10 Melamine phosphate.Figure 7.11 Modified melamine-formaldehyde resin.Figure 7.12 Macromolecular nitrogen-phosphorus intumescent flame retardant (...Figure 7.13 Hexaphenoxycyclotriphosphazene.Figure 7.14 N -β-(Aminoethyl)-γ-aminopropyltrimethoxysilane.Figure 7.15 Tris(1-chloro-2-isopropyl) phosphate.Figure 7.16 Synthesis of a flame retardant polyol (78).Figure 7.17 Synthesis of HDPCP (86).Figure 7.18 2-[Anilino-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phen...Figure 7.19 Amino trimethylene phosphonic acid.Figure 7.20 Synthesis of bis((dimethoxyphosphoryl)methyl) phenyl phosphate (...Figure 7.21 Phosphorus-containing organosilicon compounds.Figure 7.22 Reactive flame retardants.Figure 7.23 Synthesis of 2,2-diethyl-1,3-propanediol phosphoryl melamine (10...Figure 7.24 N , N -Bis(2-hydroxyethyl acrylate) aminomethyl phosphonic acid die...Figure 7.25 Synthesis of diethyl- N , N -bis(2-hydroxyethyl) phosphoramide (114)...Figure 7.26 10-Hydroxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.

8 Chapter 8Figure 8.1 MKT-1 and MKT-2.Figure 8.2 Synthesis of DDPSi-FR (21).Figure 8.3 1,2,3,4-Butane tetracarboxylic acid.Figure 8.4 Citric acid.Figure 8.5 Sulfamic acid.Figure 8.6 LOI and flame retardant and aging (39). RTFOT: Rolling thin film ...Figure 8.7 3-Aminopropyl triethoxy silane.Figure 8.8 Oil absorption with different contents of silane coupling agent (...Figure 8.9 Bis( N , N -diethyl)(2-methoxyethoxy)methylphosphonamidate.Figure 8.10 (4-Methoxy)-phenoxy pentafluorocyclotriphosphazene.Figure 8.11 Phosphorus-containing molecules.Figure 8.12 N -Ethyl-2-methoxypyrrolinium bis(fluorosulfonyl)imide.Figure 8.13 Ethoxy(pentafluoro)cyclotriphosphazene.Figure 8.14 Poly[bis-(ethoxyethoxyethoxy)phosphazene].Figure 8.15 1,1,2,2-Tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether.

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