Ali Morsali - Functional Metal-Organic Frameworks

1 Cover

2 Title page

3 Copyright

4 Preface

5 1 Introduction to Functional Metal–Organic Frameworks 1.1 Coordination Polymers 1.2 Metal–Organic Frameworks 1.3 Functional Metal–Organic Frameworks References

6 2 Amine Decorated Metal–Organic Frameworks 2.1 General Chemical Properties of Amine Function 2.2 Function–Application Properties 2.3 Function–Structure Properties References

7 3 Azo and Azine Decorated Metal–Organic Frameworks 3.1 General Chemical Properties of Azine and Azo Functions 3.2 Function–Application Properties 3.3 Function-Structure Properties References

8 4 Imidazolium and Pyridinium Decorated Metal-Organic Frameworks 4.1 Imidazolium Functionalized Metal–Organic Frameworks 4.2 Pyridinium Functionalized Metal–Organic Frameworks References

9 5 Heterocyclic Azine Decorated Metal-Organic Frameworks 5.1 General Chemical Properties of Heterocyclic Azine Functions 5.2 Function–Application Properties 5.3 Function–Structure Properties References

10 6 Heterocyclic Azole Decorated Metal-Organic Frameworks 6.1 General Chemical Properties of Heterocyclic Azole Functions 6.2 Function–Application Properties 6.3 Function–Structure Properties References

11 7 Functional Metal–Organic Frameworks by Oxygen and Sulfur Based Functions 7.1 Functionalized Metal–Organic Frameworks by Oxygen Based Functions 7.2 Functionalized Metal–Organic Frameworks by Sulfur Based Functions References

12 8 Urea and Amide Decorated Metal-Organic Frameworks 8.1 Functionalized Metal–Organic Frameworks by Amide Function 8.2 Functionalized Metal–Organic Frameworks by Urea Function 8.3 Functionalized Metal–Organic Frameworks by Squaramide Function References

13 9 Carbonyl, Carboxy and Imide Functionalized Metal–Organic Frameworks 9.1 Functionalized Metal–Organic Frameworks by Carbonyl Function 9.2 Functionalized Metal–Organic Frameworks by Carboxy Function 9.3 Functionalized Metal–Organic Frameworks by Imide Function References

14 10 Fluorine and Phosphonate Functional Metal–Organic Frameworks 10.1 Functionalized Metal–Organic Frameworks by Phosphonic Acid/Phosphonate Functions 10.2 Functionalized Metal–Organic Frameworks by Fluorine Function References

15 Index

16 End User License Agreement

1 Chapter 1 Figure 1.1Representation of CPs building blocks, synthesis and dimensionality. Figure 1.2Depiction of MOF-5 (Zn 4O(BDC) 3) as one of the most well-known MOFs. M... Figure 1.3Three strategies for functionalization of MOFs. Figure 1.4Function–structure and function–application properties of functional ... Figure 1.5Different application of functional or multi-functional MOF-based mat... Figure 1.6Classification of organic functional groups which are applied in synt... Figure 1.7Common coordinating functional groups in the structure of FMOFs. Figure 1.8Functional groups as guest-interactive sites inside the structure of ...

2 Chapter 2 Figure 2.1Application of dmen-Mg 2(dobpdc) in selective capture-release of carbo... Figure 2.2Application of [Cd(ATAIA)].4H 2O in detection of TNP. (a) Schematic re... Figure 2.33 dimensional framework of bio-MOF-1 along the c crystallographic dir... Figure 2.4Application of [Zn 2(TPOM)(NH 2–BDC) 2]∙4H 2O in detection of Cr(III) ion... Figure 2.5Application of NH 2-MIL-125 (Ti) and -MIL-125 (Ti) in oil denitrogena... Figure 2.6Possible catalytic mechanism by amine function in Knoevenagel reactio... Figure 2.7Application of UiO-66-NH 2in removal of harmful gases. Removal and de... Figure 2.8Application of UiO-66-NH 2in aqueous media detection of NO(g). (a) Pr... Figure 2.9Application of MIL-88(Fe)-NH 2in photocatalytic degradation of Cr(VI)...

3 Chapter 3 Figure 3.1Application of TMU-4, TMU-5 and TMU-6 in knoevenagel reaction. (a) De... Figure 3.2Application of RhB@TMU-5 composite in 2D detection of picric acid. (a... Figure 3.3Application of TMU-5 in oil adsorptive denitrogenation. (a) Possible ... Figure 3.4Representation of applied ligand, functional pores and 3D frameworks ... Figure 3.5Photoisomeriation characterization of Cu 2(F 2AzoBDC) 2(dabco). (a) Stru... Figure 3.6Application of IRMOF-74 in on-command cargo release of dye molecules.... Figure 3.7Application of azo-MOF in photo-responsive capture-release of Ar and ... Figure 3.8Structural strict hindrance in [Cu 2(AzoBPDC) 2(BiPy)] and [Cu 2(NDC) 2(A... Figure 3.9Representation of the non-functional and azo functionalized ligands a... Figure 3.10Two ways to introduce azo-functionalized molecules into MOFs. (a) Az... Figure 3.11Structural combination of azine and azo pillar spacers.

4 Chapter 4 Figure 4.1Resonance forms of imidazolium ring with carbene formation and metala... Figure 4.2Representation of possible interactions between metal ion and carbeni... Figure 4.3Applied synthesis approaches for construction of NHC–metal centers in... Figure 4.4Application of (I-)Meim-UiO-66 in cycloaddition reaction of CO 2with ... Figure 4.5Application of ZnL–Pd in Sonogashira cross-coupling reaction. (a) Son... Figure 4.6Application of In-L is selective removal of anionic dyes. (a) 3D stru... Figure 4.7Application of Fe-MOF, Im@Fe-MOF and Im-Fe-MOF in proton conductivity... Figure 4.8Effects of the number of imidazolium rings on the structure [29]. Figure 4.9Application of ZJU-56-0.20 in two-photon adsorption. (a) Structure of... Figure 4.10Electron excitation process in materials by single and multiphoton a... Figure 4.11Application of [Zn(p-CPBPY)(HBTC)]∙H 2O in UV light detection. (a) th... Figure 4.12Charge separated surface of a MOF-framework based on 1,1’-bis(3,5-di... Figure 4.13The ligand used for construction of zwitterionic MOF for CO 2adsorpt...

5 Chapter 5 Figure 5.1Combination of chemical properties of N-heterocyclic azine functions. Figure 5.2Application of ZJU-5 in acetylene storage. (a) Structure H 4PDDI ligan... Figure 5.3Application of ZJNU-43, ZJNU-44 and ZJNU-45 in CO 2capture. (a) Struc... Figure 5.4Depiction of applied structures by Chen and coworkers in methane stor... Figure 5.5The idea of synthesis of UTSA-110 with optimized porosity and high de... Figure 5.6Application of bio-MF-11 in CO 2capture. (a) Co(II)-adeninate-acetate... Figure 5.7Application of Eu(III)-pdc in photoluminescence detection of Cu(II) i... Figure 5.8Application of Zn-TATB ( 2) in colorimetric detection of N,N’-dimethyl... Figure 5.9Application of TMU-34 in colorimetric detection of chloroform. (a) 3D... Figure 5.10Application of UiO-66(dhtz) in detection of oxidizing gases. (a) Int... Figure 5.11Application of TMU-34(-2H) in ion detection. (a) Effect of the solve... Figure 5.12Application of [(WS 4Cu 4)I 2(dptz) 3] 3DMF in solvatochromism. (a) The ... Figure 5.13Illustration of crystal structure of [Gd 2Mn 3(PZTC) 4(H 2O) 12]·5H 2O [67... Figure 5.14Illustration of some groups of ligands with similar coordinating con... Figure 5.15Illustration of two groups of ligands for discussion about the roles... Figure 5.16Combination of some ligands with straight chain with carboxy or N-do...