Ali Morsali - Functional Metal-Organic Frameworks

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Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs.
In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

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Figure 16 Classification of organic functional groups which are applied in - фото 8

Figure 1.6 Classification of organic functional groups which are applied in synthesis of FMOFs based on their chemical characteristics and structural properties.

Figure 17 Common coordinating functional groups in the structure of FMOFs - фото 9

Figure 1.7 Common coordinating functional groups in the structure of FMOFs.

Guest-interactive functions are those enabling to interact with guest-molecules for special purpose. In this regard, the guest-interactive functions must remain free during the synthesis of FMOFs or introduced in the framework through post-synthesis modification. Almost all functions applied as guest interactive site to sensitize the FMOFs to special guest.

The next chapters of this book are structured based on these two approaches and effects of any function on the structure and application of FMOFs are discussed in details.

Figure 18 Functional groups as guestinteractive sites inside the structure of - фото 10

Figure 1.8 Functional groups as guest-interactive sites inside the structure of FMOFs and position of some of common functional groups.

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