Ali Morsali - Functional Metal-Organic Frameworks

6 Chapter 6 Figure 6.1Application of Cr 3(BTC) 2in selective O 2capture and release. (a) Cry... Figure 6.2.Application of Cr-BTT in selective O 2capture and release. (a) Cryst... Figure 6.3.Application of Co-BTTri and Co-BDTriP in selective O 2capture. (a) S... Figure 6.4.Application of TIF-1 in conjugate addition reaction. (a) Formation o... Figure 6.5.Application of Sm-MOF in excited-state intramolecular proton transfe... Figure 6.6.Synthesis, coordination mode, and formulae for 3D energetic [Cu(atrz... Figure 6.7.Application of [M(N 3) 2(atrz)] n(M = Co 1, Cd 2) as energetic materia... Figure 6.8.Comparison of general properties of heterocyclic azoles [58]. Figure 6.9.Coordination modes of heterocyclic azole N-based functions. Figure 6.10.Similarity between carboxylate and pyrazolate coordination modes in... Figure 6.11.Similarity between carboxylate and pyrazolate coordination modes in... Figure 6.12.From left to right: an alkyl−alkyl imidazolium cation; an imidazole...

7 Chapter 7 Figure 7.1.Possible interaction between azoxy functionalized framework and Pb(I... Figure 7.2.Application of Eu-L2 and Tb-L2 in metal ion detection. (a) structure... Figure 7.3.Representation of oxadiazole, thiadiazole, and selenadiazole ligands... Figure 7.4.Application of Zn–H, Zn–OH and Zn–NH 2in CO 2adsorption. (a) Schemat... Figure 7.5.Possible host–guest interactions between CO 2molecules and hydroxy f... Figure 7.6.The role of free hydroxy function in activation of epoxy ring in CO 2... Figure 7.7.H 2BDC based ligand for construction of MOFs based on hard-soft chemi... Figure 7.8.Structure of MOF-5, MOF-74, UiO-66 and UiO-66(SH) 2. In the UiO-66(SH... Figure 7.9.Protection of H 2BDC-(OH) 2by acetoxy groups and deprotection of H 2BD... Figure 7.10.Application of Zr-btdc in gas adsorption. (a) Structural representa... Figure 7.11.Application of FJI-H12 in Hg(II) removal. (a) Structure of FJI-H12.... Figure 7.12.Adsorption of Hg ions on thiol sites of Zr-DMBD [54]. Figure 7.13.Application of ASMOF-5 in Pd(II) detection. (a) Crystal structure o... Figure 7.14.(a) Schematic illustration of the degradation of Cr(VI) by thiol-co... Figure 7.15.Photophysical properties of UiO-66-(SO 3H) 2, UiO-66-(SH) 2and UiO-66... Figure 7.16.Application of UiO-66(SO 3H) 2in proton conductivity. (a) Synthesis ... Figure 7.17.Application of PSM-1 and PSM-2 in proton conductivity. (a) Synthesi... Figure 7.18.Application of MIL-101-Cr-SO 3Ag in selective uptake of ethylene. (a... Figure 7.19.Application of MIL-101-SO 3H in removal of cationic dyes. Effect of ... Figure 7.20.Light-enhanced acid-catalytic reaction over MIL-101-SO 3H, in which ... Figure 7.21.Proposed acetalization reaction mechanism and determination of firs...

8 Chapter 8 Figure 8.1.Coordination environment and crystal structure of isoreticular MFM-f... Figure 8.2.Application of isoreticular MFM-frameworks in gas adsorption. (a) Hi... Figure 8.3.Application of NJU-Bai49 in selective CO 2adsorption. (a) [Sc 3(μ 3-O)... Figure 8.4.Application of NJU-Bai-17 in acetylene storage. (a) The X-ray crysta... Figure 8.5.Application of NJU-Bai-45 in methane storage. (a) Applied ligands in... Figure 8.6.Representation of the applied ligand in the structure of PCN-61 and ... Figure 8.7.Application of TMU-56 in Pb(II) removal. (a) Crystal structure of TM... Figure 8.8.Structural representation of NOTT-125 and possible interactions betw... Figure 8.9.(a) 3D framework of [Ln 2(bdpo) 1.5(DMA) 3(H 2O)]·5H 2O (b) H 4bdpo to Ln ... Figure 8.10.Application of TMU-32S-65% in Hg(II) removal. (a) L2-L ligand excha... Figure 8.11.Effect of introducing amide function in the main-chain of the MOF s... Figure 8.12.Effects of conformation of amide-function on the constructed compou... Figure 8.13.(a) Non-functional and amide-functionalized ligands for constructio... Figure 8.14.(a) Non-functional and amide-functionalized ligands for constructio... Figure 8.15.Host–guest interactions of urea. (a) Hydrogen bonding interaction b... Figure 8.16.Structural representation of [Zn 2( L1) 2(bipy)] (a) and [Zn 2( L1) 2(bpe... Figure 8.17.Structure of EDPU ligand (a), crystal structure of [Ni(EDPU) 2(H 2O) 2... Figure 8.18.Structure, applied ligands in synthesis of NU-601 (a) Application o... Figure 8.19.Application of urea decorated MOFs as hydrogen bond donor organocat... Figure 8.20.Effects of urea function in the main-chain on the structure of MOFs... Figure 8.21.Representation of urea and triazole functionalized ligands for cons... Figure 8.22.Structural change of [Zn 4O( L) 3(DMF) 2] nafter activation by CS 2[86]... Figure 8.23.Significantly different characteristics between urea and squaramide... Figure 8.24.Application of UiO-67-Squar/bpdc in Friedel–Crafts reaction. Figure 8.25.Comparison between carbonyl based functions.

9 Chapter 9 Figure 9.1Application of Tb-BCB in detection of small organic molecules. (a) St... Figure 9.2Application of Cu-cdip in gas adsorption. (a) Structure of the H 4cdip... Figure 9.3Application of DUT-122 in organic solvent sensing. (a) Structure of D... Figure 9.4Application of Eu-fdc in ratiometric temperature sensing. (a) Schemat... Figure 9.5Carbonylation of sp 3atoms for construction of rigid and polar carbon... Figure 9.6Coordination modes of the carboxylate ligands [10]. Figure 9.7Synthesis of [CuCl(BNA) 2]∙Cl(H 2O) 4through control over pH. (a) Struct... Figure 9.8Post-synthesis CO 2insertion into the structure of UiO-67(dcppy). (a) ... Figure 9.9Molecular Representations of NU-1000 (top) and Depictions of Solvent-... Figure 9.10Synthesis of UiO-66-ox by Hupp and coworkers through solvent assiste... Figure 9.11Application of UiO-66(COOH) 2in CO 2adsorption. (a) The UiO-66(Zr)-(CO... Figure 9.12Inorganic nodes of some MOFs based on terphthalic acid linker. Combi... Figure 9.13Structure of imide functionalized aromatic cores. Figure 9.15Application of FJU-101 in methane storage. Nanosized cage (a) and 3D... Figure 9.16Application of 1 and 1−Li +in H 2storage. (a) Crystal structure of 1...

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2 Table of Contents

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4 Copyright

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