Metal-Organic Frameworks with Heterogeneous Structures

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For the first time, in this book, a new view of metal-organic frameworks (MOFs) has been presented: MOFs with heterogeneous structures. In this field, there are different levels of understanding we need to consider. So, the principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications have been thoroughly reported. According to that there is no book that covers whole of the aspects of complexity in MOFs with heterogeneous structures, our findings can be as essential concepts with introducing complexity to design the new platforms of materials with advanced and better properties in the future.

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9 Chapter 9Figure 9.1 (a) H 4PANAD structure. (b) HHU-1 network with varying size pores (two...Figure 9.2 Heterogeneous pores due to missing node or ligand [28, 29].Figure 9.3 An example of MOF-based porous carbon (NHOPC) with multiporosity synt...Figure 9.4 Examples of Cr-MILs as mesoMOFs with two types of mesocages [43, 44].

10 Chapter 10Figure 10.1 Schematic representation of bio-MOF composite [21].Figure 10.2 Heteroepitaxially grown hybrid IRMOF-3@1 and structures of IRMOF-1 a...Figure 10.3 Optical micrographs: (a) hybrid IRMOF-3@1, (b) IRMOF-1@3. (IRMOF-1: ...Scheme 10.1 Suggested mechanism of carbon dioxide cycloaddition with epoxide by ...Figure 10.4 Isostructural Eu/Tb mixed MOFs with different triplet energy levels ...

Guide

1 Cover

2 Table of Contents

3 Title Page

4 Copyright

5 List of Illustrations

6 List of Tables

7 List of Schemes

8 Preface

9 Abbreviations

10 Begin Reading

11 Index

12 Also of Interest

13 End User License Agreement

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Scrivener Publishing100 Cummings Center, Suite 541J Beverly, MA 01915-6106

Publishers at Scrivener

Martin Scrivener ( martin@scrivenerpublishing.com) Phillip Carmical ( pcarmical@scrivenerpublishing.com)

Metal-Organic Frameworks With Heterogeneous Structures

Ali Morsali

and

Kayhaneh Berijani

Department of Chemistry, Tarbiat Modares University, Tehran, Islamic Republic of Iran

This edition first published 2021 by John Wiley Sons Inc 111 River Street - фото 1

This edition first published 2021 by John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA and Scrivener Publishing LLC, 100 Cummings Center, Suite 541J, Beverly, MA 01915, USA

© 2021 Scrivener Publishing LLC

For more information about Scrivener publications please visit www.scrivenerpublishing.com.

All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, except as permitted by law. Advice on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.

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For details of our global editorial offices, customer services, and more information about Wiley products visit us at www.wiley.com.

Limit of Liability/Disclaimer of WarrantyWhile the publisher and authors have used their best efforts in preparing this work, they make no representations or warranties with respect to the accuracy or completeness of the contents of this work and specifically disclaim all warranties, including without limitation any implied warranties of merchantability or fitness for a particular purpose. No warranty may be created or extended by sales representatives, written sales materials, or promotional statements for this work. The fact that an organization, website, or product is referred to in this work as a citation and/or potential source of further information does not mean that the publisher and authors endorse the information or services the organization, website, or product may provide or recommendations it may make. This work is sold with the understanding that the publisher is not engaged in rendering professional services. The advice and strategies contained herein may not be suitable for your situation. You should consult with a specialist where appropriate. Neither the publisher nor authors shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read.

Library of Congress Cataloging-in-Publication Data

ISBN 978-1-119-79204-8

Cover image: Pixabay.comCover design by Russell Richardson

Set in size of 12pt and Minion Pro by Manila Typesetting Company, Makati, Philippines

Printed in the USA

10 9 8 7 6 5 4 3 2 1

List of Illustrations

1 Figure 1.1Simple description of 3D MOF chemistry.

2 Figure 1.2Some examples of metal nodes, organic linkers, and MOFs (definition of atom types: blue: metal; red: oxygen; purple: nitrogen; gray: carbon; and green: chlorine).

3 Figure 1.3Some examples of MOFs synthesis methods.

4 Figure 2.1Simple language to understand concept of complexity.

5 Figure 2.2Overview of this book based on the effective factors in the construction MOFs with heterogeneous structures.

6 Figure 2.3Classification of complexity key factors in MOFs (further details in text).

7 Figure 2.4A cost-effective mixed-metal mixed-ligand MOF, which exhibits highly efficient photocatalytic H2 generation.

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