Handbook of Biomass Valorization for Industrial Applications

5) Other environmental impacts

Production and use of biodiesel may result emissions of particulate matter, SO 2, CO, NO x, and various volatile organic carbons which results directly or indirectly in respiratory and other cardiovascular diseases [63]. Other environmental impacts depend on assumptions like type of vehicle in which biofuels are used, acidification and eutrophication of land and lakes. These impacts arise due to use of fertilizers and associated emissions of acid gases and nutrients to air and water.

1. Alonso, D.M., Bond, J.Q., Dumesic, J., Catalytic conversion of biomass to biofuels. Green Chem ., 12, 1493–1513, 2010 (October).

2. Parveen, F., Ahmad, K., Upadhyayula, S., Catalytic Conversion of Biomass Derived Cellulose to 5-Hydromethyl Furfural, in: Integrating Green Chemistry and Sustainable Engineering , pp. 113–163, John Wiley & Sons, Inc., USA, 2019.

3. Ahmad, K., Parveen, F., Upadhyayula, A., Upadhyayula, S., Heterogeneous Catalytic Conversion of Greenhouse Gas {CO}2 to Fuels, in: Integrating Green Chemistry and Sustainable Engineering , pp. 57–80, John Wiley & Sons, Inc., 2019.

4. Chheda, J.N., Huber, G.W., Dumesic, J.A., Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals. Angew. Chem.—Int. Ed ., 46, 38, 7164–7183, 2007.

5. Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., Beltramini, J., Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels. Chem. Soc. Rev ., 40, 11, 5588, 2011.

6. Parveen, F., Patra, T., Upadhyayula, S., Hydrolysis of microcrystalline cellulose using functionalized Bronsted acidic ionic liquids—A comparative study. Carbohydr. Polym ., 135, 2016, 280–284, 2015.

7. Parveen, F., Gupta, K., Upadhyayula, S., Synergistic effect of chloro and sulphonic acid groups on the hydrolysis of microcrystalline cellulose under benign conditions. Carbohydr. Polym ., 159, 146–151, 2017.

8. Parveen, F., Jaiswal, M., Upadhyayula, S., Effect of linkers (aliphatic/aromatic) and anions on the activity of sulfonic acid functionalized ionic liquids towards catalyzing the hydrolysis of microcrystalline cellulose—An experimental and theoretical study. Renew. Energy , 121, 590–596, 2018.

9. Schutyser, W., Renders, T., Van Den Bosch, S., Koelewijn, S.F., Beckham, G.T., Sels, B.F., Chemicals from lignin: An interplay of lignocellulose fractionation, depolymerisation, and upgrading. Chem. Soc. Rev ., 47, 3, 852–908, 2018.

10. Babu, B.V., Biomass pyrolysis: A state-of-the-art review. Biofuel. Bioprod. Bior ., 2, 393–414, 2008.

11. Holladay, J.E., Bozell, J.J., White, J.F., J.D., Top value added chemicals from biomass volume I— Results of screening for potential candidates from sugars and synthesis gas , Department of Energy, United States, 2004.

12. Parveen, F., Patra, T., Upadhyayula, S., A structure-activity relationship study using DFT analysis of Bronsted–Lewis acidic ionic liquids and synergistic effect of dual acidity in one-pot conversion of glucose to value-added chemicals. New J. Chem ., 42, 2, 1423–1430, 2018.

13. Parveen, F. and Upadhyayula, S., Efficient conversion of glucose to HMF using organocatalysts with dual acidic and basic functionalities—A mechanistic and experimental study. Fuel Process. Technol ., 162, 30–36, 2017.

14. Kumar, K., Khatri, V., Parveen, F., Kashyap, H.K., Upadhyayula, S., Synthesis of an oxygenated fuel additive from a waste biomass derived aldehyde using a green catalyst: An experimental and DFT study. Sustain. Energy Fuels , 4, 6, 2924–2936, 2020.

15. Ghosh, D., Dasgupta, D., Agrawal, D., Kaul, S., Adhikari, D.K., Kurmi, A.K., Arya, P.K., Bangwal, D., Negi, M.S., Fuels and chemicals from lignocellulosic biomass: An integrated biorefinery approach. Energy Fuels , 29, 5, 3149–3157, 2015.

16. Tong, X., Chen, H., Hu, J., Bi, Y., Sun, Z., Fan, W., The Efficient and Sustainable Pyrolysis and Gasification of Biomass by Catalytic Processes. ChemBioEng Rev ., 2, 3, 157–174, 2015.

17. de Wild, P., Reith, H., Heeres, E., Biomass pyrolysis for chemicals, Biofuels, 2, 185-208, 2011.

18. Mohan, D., Pittman, C.U., Steele, P.H., Pyrolysis of wood/biomass for bio-oil: A critical review. Energy Fuels , 20, 3, 848–889, 2006.

19. Collard, F.X., Blin, J., Bensakhria, A., Valette, J., Influence of impregnated metal on the pyrolysis conversion of biomass constituents. J. Anal. Appl. Pyrolysis , 95, 213–226, 2012.

20. Wildschut, J., Mahfud, F.H., Venderbosch, R.H., Heeres, H.J., Hydrotreatment of Fast Pyrolysis Oil Using Heterogeneous Noble-Metal Catalysts. Ind. Eng. Chem. Res ., 48, 23, 10324–10334, 2009.

21. Stefanidis, S., Kalogiannis, K., Iliopoulou, E.F., Lappas, A.A., Triguero, J.M., Navarro, M.T., Chica, A., Rey, F., Mesopore-modified mordenites as catalysts for catalytic pyrolysis of biomass and cracking of vacuum gasoil processes. Green Chem ., 15, 6, 1647, 2013.

22. Yu, Y., Zeng, Y., Zuo, J., Ma, F., Yang, X., Zhang, X., Wang, Y., Improving the conversion of biomass in catalytic fast pyrolysis via white-rot fungal pretreatment. Bioresour. Technol ., 134, 198–203, 2013.

23. Cheng, Y.T., Jae, J., Shi, J., Fan, W., Huber, G.W., Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/ZSM-5 catalysts. Angew. Chem.—Int. Ed ., 51, 6, 1387–1390, 2012.

24. Lu, Q., Zhang, Z.B., Yang, X.C., Dong, C.Q., Zhu, X.F., Catalytic fast pyrolysis of biomass impregnated with K3PO 4 to produce phenolic compounds: Analytical Py-GC/MS study. J. Anal. Appl. Pyrolysis , 104, 139–145, 2013.

25. Hussain, Z., Khan, K.M., Khan, A., Ullah, S., Karim, A., Perveen, S., The conversion of biomass into liquid hydrocarbon fuel by two step pyrolysis using cement as catalyst. J. Anal. Appl. Pyrolysis , 101, 90–95, 2013.

26. Shadangi, K.P. and Mohanty, K., Production and characterization of pyrolytic oil by catalytic pyrolysis of Niger seed. Fuel , 126, 109–115, 2014.

27. Tang, Q., Chen, Y., Yang, H., Liu, M., Xiao, H., Wu, Z., Chen, H., Naqvi, S.R., Prediction of Bio-oil Yield and Hydrogen Contents Based on Machine Learning Method: Effect of Biomass Compositions and Pyrolysis Conditions. Energy Fuels , 34, 9, 11050–11060, 2020.

28. Bulushev, D.A. and Ross, J.R.H., Catalysis for conversion of biomass to fuels via pyrolysis and gasification: A review. Catal. Today , 171, 1, 1–13, 2011.

29. Udomsirichakorn, J. and Salam, P.A., Review of hydrogen-enriched gas production from steam gasification of biomass: The prospect of CaO-based chemical looping gasification. Renewable Sustain. Energy Rev ., 30, 565–579, 2014.

30. Vamvuka, D., Karouki, E., Sfakiotakis, S., Gasification of waste biomass chars by carbon dioxide via thermogravimetry. Part I: Effect of mineral matter. Fuel , 90, 3, 1120–1127, 2011.

31. Vamvuka, D., Karouki, E., Sfakiotakis, S., Salatino, P., Gasification of waste biomass chars by carbon dioxide via thermogravimetry-effect of catalysts. Combust . Sci. Technol ., 184, 1, 64–77, 2012.