Roberto Ballini - Nitroalkanes

13 Chapter 12Scheme 12.1 Synthesis of α-ketoacids 2.Figure 12.1 1, n -Dicarbonyls.Scheme 12.2 Synthesis of 1,2-dicarbonyls 8.Figure 12.2 Synthetic equivalents of 3and 4.Scheme 12.3 Synthesis of β-ketoesters 12.Scheme 12.4 Synthesis of 1,3-diketones 16.Scheme 12.5 Synthesis of β-ketoesters 20.Scheme 12.6 Synthesis of 1,4-diketones 24.Scheme 12.7 One-pot synthesis of 1,4-diketones 27.Scheme 12.8 One-pot synthesis of 1,4,7-triketones 29.Scheme 12.9 One-pot synthesis of 1,4-diketones 31.Scheme 12.10 One-pot synthesis of 1,4-diketones 35.Scheme 12.11 One-pot synthesis of ( E )-alylidene-1,4-diones 38.Scheme 12.12 One-pot synthesis of 1,4-diketones 42aor γ-ketoaldehydes 42b....Scheme 12.13 One-pot synthesis of ( E )-enediones 46.Scheme 12.14 Synthesis of 1,4-dione 50, precursor of ketoprofen 51.Scheme 12.15 Synthesis of cyclopentenone 55, precursor of Cuparene 56.Scheme 12.16 One-pot synthesis of Allylrethrone 59.Scheme 12.17 Synthesis of ( Z )-Jasmone 62band methyl Jasmonate 63.Scheme 12.18 Synthesis of γ-ketoesters 66or γ-ketoacids 67.Scheme 12.19 Synthesis of ( R )-(+)-γ-caprolactone.Scheme 12.20 Synthesis of γ-ketoesters 69via Michael reaction.Scheme 12.21 One-pot synthesis of γ-ketodiesters 72.Scheme 12.22 One-pot synthesis of γ-ketodiesters 75.Scheme 12.23 Synthesis of exo -methylene butyrolactones 79.Scheme 12.24 Synthesis of γ-ketoacids 81or γ-ketoaldehydes 83.Scheme 12.25 Synthesis of γ-keto α,β-unsaturated esters 86.Scheme 12.26 Synthesis of 1,5-diketones 91.Scheme 12.27 Synthesis of 1,5-diketones 94.Scheme 12.28 Synthesis of δ-ketoester 97.

14 Chapter 13Scheme 13.1 Synthesis of Chalcogran 7.Figure 13.1 Some representative examples of spiroketals.Figure 13.2 Most common spiroketal structures I–V.Scheme 13.2 Synthesis of symmetric 2,7-dialkyl-1,6-dioxaspiro[4.4]nonanes 10...Scheme 13.3 Enantioselective synthesis of 12.Scheme 13.4 Enantioselective synthesis of ( E )- 18.Scheme 13.5 Synthesis of spiro[4.5]decane 22.Scheme 13.6 Synthesis of γ-Rubromycin 29.Scheme 13.7 Synthesis of spiro[4.6]undecanes 33.Scheme 13.8 Synthesis of 2,7-dialkyl-1,6-dioxaspiro[4.6]undecanes 40.Scheme 13.9 Synthesis of 1,7-dioxaspiro[5.5]undecanes 45aand dioxaspiro[5.6...Scheme 13.10 Synthesis of 2-methyl-1,7-dioxaspiro[5.6]dodecane 52.

1 Cover

2 Table of Contents

3 Begin Reading

1 iii

2 iv

3 v

4 xiii

5 xv

6 xvii

7 xix

8 xx

9 xxi

10 1

11 2

12 3

13 4

14 5

15 6

16 7

17 8

18 9

19 10

20 11

21 12

22 13

23 14

24 15

25 16

26 17

27 19

28 20

29 21

30 22

31 23

32 24

33 25

34 26

35 27

36 28

37 29

38 30

39 31

40 32

41 33

42 34

43 35

44 36

45 37

46 38

47 39

48 40

49 41

50 42

51 43

52 44

53 45

54 46

55 47

56 48

57 49

58 50

59 51

60 52

61 53

62 54

63 55

64 56

65 57

66 58

67 59

68 60

69 61

70 62

71 63

72 64

73 65

74 66

75 67

76 68

77 69

78 70

79 71

80 72

81 73

82 74

83 75

84 76

85 77

86 78

87 79

88 80

89 81

90 82

91 83

92 84

93 85

94 86

95 87

96 88

97 89

98 90

99 91

100 92

101 93

102 94

103 95

104 96

105 97

106 98

107 99

108 100

109 101

110 102

111 103

112 104

113 105

114 107

115 108

116 109

117 110

118 111

119 112

120 113

121 114

122 115

123 116

124 117

125 118

126 119

127 120

128 121

129 122

130 123

131 124

132 125

133 126

134 127

135 128

136 129

137 130

138 131

139 132

140 133

141 134

142 135

143 136

144 137

145 138

146 139

147 140

148 141

149 142

150 143

151 144

152 145

153 146

154 147

155 148

156 149

157 151

158 152

159 153

160 154

161 155

162 156

163 157

164 158

165 159

166 160

167 161

168 162

169 163

170 164

171 165

172 166

173 167

174 168

175 169

176 170

177 171

178 172

179 173

180 174

181 175

182 176

183 177

184 178

185 179

186 180

187 181

188 182

189 183

190 184

191 185

192 186

193 187

194 188

195 189

196 190

197 191

198 192

199 193

200 194

201 195

202 196

203 197

204 198

205 199

206 200

207 201

208 202

209 203

210 204

211 205

212 206

213 207

214 209

215 210

216 211

217 212

218 213

219 214

220 215

221 216

222 217

223 218

224 219

225 220

226 221

227 222

228 223

229 224

230 225

231 226

232 227

233 228

234 229

235 230

236 231

237 232

238 233

239 234

240 235

241 236

242 237

243 238

244 239

245 240

246 241

247 242

248 243

249 244

250 245

251 246

252 247

253 248

254 249

255 250

256 251

257 252

258 253

259 254

260 255

261 256

262 257

263 258

264 259

265 260

266 261

267 262

268 263

269 264

270 265

271 266

272 267

273 268

274 269

275 270

276 271

277 272

278 273

279 274

280 275

281 276

282 277

283 278

284 279

285 280

286 281

287 282

288 283

289 284

290 285

291 286

292 287

293 288

294 289

295 290

296 291

297 292

298 293

299 294

300 295

301 296

302 297

303 298

304 299

Roberto Ballini

Alessandro Palmieri

Authors

Prof. Roberto BalliniUniversity of Camerino Chemistry Division Via S. Agostino 1 62032 Camerino Italy

Prof. Alessandro PalmieriUniversity of Camerino Chemistry Division Via S. Agostino 1 62032 Camerino Italy

CoverCover Image: Courtesy of Ballini

Читать дальше