Engineering Solutions for CO2 Conversion

16 Chapter 16Figure 16.1 Alternating copolymerization of CO 2with (a) propylene oxide, (b...Figure 16.2 Oxidation of ( R ) ‐ limonene via two different routes to diff...Scheme 16.1 Copolymerization of CO 2and epoxides in three elementary steps: ...Figure 16.3 Reaction coordinate diagram for the coupling of (a) CHO and (b) ...Scheme 16.2 Degradation mechanism for PPC: chain scission (a) and backbiting...Figure 16.4 Poly(cyclohexene carbonate) (a), poly(propylene carbonate) (b), ...Figure 16.5 Representation of part of the repeating unit in two different zi...Figure 16.6 Types of homogeneous catalysts active in the copolymerization of...Scheme 16.3 Proposed copolymerization mechanism for BDI–Zn catalysts (a) and...Figure 16.7 Flexibly tethered bimetallic zinc complex.Figure 16.8 Structure of the β‐diiminato–zinc–NTMS 2complex 3and its ORTEP ...Figure 16.9 Macrocyclic diphenolate complexes with Zn or Mg as a central met...Figure 16.10 Postulated mechanism for the terpolymerization reaction of BBL,...Figure 16.11 Active initiators for the copolymerization of CO 2and limonene ...Figure 16.12 Postulated mechanism for the copolymerization of limonene oxide...

17 Chapter 17Figure 17.1 Schematic representation of the MOF structural levels and compon...Figure 17.2 Examples of different applications involving MOF materials.Figure 17.3 Generation of open metal site (OMS) illustrative example.Scheme 17.1 Synthesis of cyclic carbonates from an epoxide.Figure 17.4 Proposed mechanism of CO 2cycloaddition.Scheme 17.2 Oxidative carboxylation reaction of styrene.

18 Chapter 18Figure 18.1 Energy efficiency of plasma‐assisted CO 2reduction as a function...Figure 18.2 Illustration of different electron impact driven dissociation pr...Figure 18.3 Channels for activation of CO 2as a function of the reduced elec...Figure 18.4 Various plasma reactors used for chemical conversions: dielectri...Figure 18.5 Schematic representation of various plasma–catalyst interactions...Figure 18.6 Schematic of the dissociative surface adsorption of various acti...Figure 18.7 Comparison of literature data for CO 2splitting in various plasm...Figure 18.8 Comparison of literature data for the dry reforming of methane i...Figure 18.9 Comparison of literature data for CO 2hydrogenation in various p...Figure 18.10 Comparison of literature data for artificial photosynthesis in ...Figure 18.11 Typical timescales of plasma‐phase reactions and catalytic surf...Figure 18.12 Industrial plasma‐driven ozone generators (DBD reactors) for 60...

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