Rajender Boddula - Fundamentals of Solar Cell Design

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Solar cells are semiconductor devices that convert light photons into electricity in photovoltaic energy conversion and can help to overcome the global energy crisis. Solar cells have many applications including remote area power systems, earth-orbiting satellites, wristwatches, water pumping, photodetectors and remote radiotelephones. Solar cell technology is economically feasible for commercial-scale power generation. While commercial solar cells exhibit good performance and stability, still researchers are looking at many ways to improve the performance and cost of solar cells via modulating the fundamental properties of semiconductors. Solar cell technology is the key to a clean energy future. Solar cells directly harvest energy from the sun’s light radiation into electricity are in an ever-growing demand for future global energy production.
Solar cell-based energy harvesting has attracted worldwide attention for their notable features, such as cheap renewable technology, scalable, lightweight, flexibility, versatility, no greenhouse gas emission, environment, and economy friendly and operational costs are quite low compared to other forms of power generation. Thus, solar cell technology is at the forefront of renewable energy technologies which are used in telecommunications, power plants, small devices to satellites. Aiming at large-scale implementation can be manipulated by various types used in solar cell design and exploration of new materials towards improving performance and reducing cost. Therefore, in-depth knowledge about solar cell design is fundamental for those who wish to apply this knowledge and understanding in industries and academics.
This book provides a comprehensive overview on solar cells and explores the history to evolution and present scenarios of solar cell design, classification, properties, various semiconductor materials, thin films, wafer-scale, transparent solar cells, and so on. It also includes solar cells’ characterization analytical tools, theoretical modeling, practices to enhance conversion efficiencies, applications and patents.

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15 Chapter 15Figure 15.1 Various device arrangements of PSC (a) n-i-p mesoscopic, (b) n-i-p p...Figure 15.2 Planckian locus in the CIE 1931 chromaticity diagram.Figure 15.3 (a) CIE RGB color matching functions, (b) CIE XYZ standard observer ...Figure 15.4 Structure of ST-PSC producing multiple-colors by the exploitation of...Figure 15.5 ST-PSC with TiO 2/SiO2 multilayer dielectric mirror integrated at the...Figure 15.6 Schematic reflection modulation of the cell producing multiple-color...Figure 15.7 Semitransparent neutral-colored dewetted planar heterojunction PSC [...Figure 15.8 The step-by-step schematic illustration of the spin coating techniqu...Figure 15.9 Illustration of energy levels of commonly used ETL, HTL, and transpa...Figure 15.10 Schematic illustration of the device architecture having (MUTAB-bas...Figure 15.11 Schematic structure of ST-SC cell and organic materials used.Figure 15.12 Devices in operation. The transparent window mode (left) allows ful...Figure 15.13 Illustration of the proposed ST-PSC stack [53].Figure 15.14 Illustration of (a) monolithic two-terminal (2T) and (b) mechanical...Figure 15.15 General schematic and energy potential diagrams of the perovskite a...

16 Chapter 16Figure 16.1 Hierarchy of generations of solar cells.Figure 16.2 (a) Schematic diagram of a flexible solar cell. (b) Image representi...Figure 16.3 Images representing examples of flexible PV panel: (a) manufacturing...Figure 16.4 Schematic diagram for R2R processing.Figure 16.5 Schematic diagram for CBD process.Figure 16.6 Typical experimental setup of CVD.Figure 16.7 Schematic diagram of the dip-coating process.Figure 16.8 Schematic showing the different stages of spin coating technique.Figure 16.9 Schematic resembling the screen printing technique.Figure 16.10 (a) Scheme of collection mode SNOM setup in transmission geometry. ...Figure 16.11 Generic spectroscopic ellipsometry (SE) configurations.Figure 16.12 Experimental setup of TRPL.Figure 16.13 Schematic diagram of ESR spectrometer experimental setup.Figure 16.14 The SEM measurement setup.Figure 16.15 I-V characteristic of solar cell.Figure 16.16 I-V characteristics measurement setup.Figure 16.17 EQE measurement setup.Figure 16.18 (a) Spectrally resolved. (b) Spatially resolved EL setup.

List of Tables

1 Chapter 2 Table 2.1 Various solar cell technologies and its efficiency. Table 2.2 Energy band gap of various absorber and metal nanoparticles. Table 2.3 Effect of various plasmonic nanostructures on solar cell technologies.

2 Chapter 6Table 6.1. Various materials used as essential parts of DSSCs with their photovo...

3 Chapter 7Table 7.1. A list of different Ru-based dye sensitizers with their photoelectroc...Table 7.2. Calculated efficacy of cells with various counter electrodes [109].

4 Chapter 8Table 8.1. The irradiation values.Table 8.2. Sun irradiation attributes.Table 8.3. Top 10 confirmed module and cells.

5 Chapter 10Table 10.1. Properties and features idealized for solar cell materials.Table 10.2. Notable performance results for c-SI SCs and modules.Table 10.3. Notable performance results for Si TFSCs.Table 10.4. Notable performance results for III-V semiconductor-based SCs.Table 10.5. Notable performance results for CIGS SCs.Table 10.6. Notable performance results for CdTe SCs.Table 10.7. Notable performance results for fullerene and non-fullerene OSCs.Table 10.8. Notable performance results for DSSCs.Table 10.9. Notable performance results of PSCs.

6 Chapter 12Table 12.1. Molecular weights and thermal data of copolymers P1 and P2 [89].

7 Chapter 14Table 14.1. Evolution and PCE of different C/Si heterojunctions [67].Table 14.2. Evolution and PCE of different C/Si heterojunctions [67].Table 14.3. Advances in X-anions/A-cations substitutions [133].Table 14.4. PV characteristic of the Sn-based perovskites [210].Table 14.5. Working spectropolarimetries [166].Table 14.6. Water network elements [182].

8 Chapter 15Table 15.1. Comparison of different photovoltaic materials and their optoelectro...Table 15.2 Summary of representative semitransparent perovskite solar cells with...Table 15.3. Summary of different single-junction and tandem semitransparent pero...

9 Chapter 16Table 16.1. Comparison chart of RSCs and FSCs.

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