Biosorption for Wastewater Contaminants

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Pollution due to various anthropogenic activities continues to increase. In terms of water pollutants, organic and inorganic pollutants are the most problematic. Although several measures have been proposed and implemented to prevent or reduce contamination, their increased concentration in water bodies has created serious concerns. Over the years, the problem has been aggravated by industrialization, urbanization and the exploitation of natural resources. The direct discharge of wastewater contaminants and their geographical mobilization have caused an increase in concentration in ground, surface, fluvial and residual waters. Extensive information about detection and disposal methods is needed in order to develop technological solutions for a ­variety of environments, both urban and rural. This book provides up-to-date information on wastewater contaminants, aimed at researchers, engineers and technologists working in this field. Conventional physicochemical techniques used to remove contaminants from wastewater include ion exchange, precipitation, degradation, coagulation, coating, membrane processes and adsorption. However, these applications have technological and economic limitations, and involve the release of large amounts of chemical reagents and by-products that are themselves difficult to remove. Biosorption – the use of organically generated material as an adsorbent – is attracting new research and scholarship. Thermally-treated calcined biomaterials may be treated to remove heavy metals from wastewater. To ensure the elimination of these contaminants, existing solutions must be integrated with intelligent biosorption functions.
will find an appreciative audience among academics and postgraduates working in the fields of environmental biotechnology, environmental engineering, wastewater treatment technology and environmental chemistry.

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Library of Congress Cataloging‐in‐Publication data applied for

HB ISBN: 9781119737599

Cover Design: Wiley

Cover Images: © Chanin Wardkhian/Getty images; krystiannawrocki/Getty Images; Image Source/Getty Images

List of Contributors

Abhishek Agrawal School of Pharmaceutical Sciences Pratap University Jaipur Rajasthan India

Pinki Rani Agrawal CSIR National Physical Laboratory New Delhi India and Academy of Scientific and Innovative Research (AcSIR) Ghaziabad Uttar Pradesh India

R. Balaji Department of Biotechnology Aarupadai Veedu Institute of Technology Chennai Tamilnadu India

João Paulo Bassin Chemical Engineering Program COPPE Federal University of Rio de Janeiro Rio de Janeiro Brazil and Civil Engineering Program COPPE Federal University of Rio de Janeiro Rio de Janeiro Brazil

Subramanyam Busetty School of Civil Engineering SASTRA Deemed University Thanjavur Tamilnadu India

Ramprasad Chandrasekaran School of Civil Engineering SASTRA Deemed University Thanjavur Tamilnadu India

B. Deepanraj Department of Mechanical Engineering Jyothi Engineering College Thrissur Kerala India

R. Devika Department of Biotechnology Aarupadai Veedu Institute of Technology Chennai Tamilnadu India

João Pedro Neves Goldenstein Civil Engineering Program COPPE Federal University of Rio de Janeiro Rio de Janeiro Brazil

Gaurav Gupta Department of Physics and Astrophysics University of Delhi New Delhi India

Ittishree G.V.M College of Pharmacy Pt. B.D. Sharma University of Health Sciences Sonipat Haryana India

Jay Mant Jha Department of Chemical Engineering Maulana Azad National Institute of Technology Bhopal Madhya Pradesh India

Noel Jacob Kaleekkal Membrane Separation Group Department of Chemical Engineering National Institute of Technology Calicut Kozhikode Kerala India

J. Kanimozhi Department of Biotechnology Kalasalingam Academy of Research and Education Krishnankoil Tamilnadu India

Ravi Kumar CSIR National Physical Laboratory New Delhi India and Academy of Scientific and Innovative Research (AcSIR) Ghaziabad Uttar Pradesh India

Vishal Mishra School of Biochemical Engineering IIT (BHU) Varanasi Uttar Pradesh India

G Nandu Membrane Separation Group Department of Chemical Engineering National Institute of Technology Calicut Kozhikode Kerala India

Rajarathinam Nithya Department of Industrial Biotechnology Government College of Technology Coimbatore Tamilnadu India

Ramesh Oraon Department of Nanoscience and Technology Central University of Jharkhand Brambe Ranchi Jharkhand India

Dan Bahadur Pal Department of Chemical Engineering Birla Institute of Technology Mesra Ranchi Jharkhand India

Camila Pesci Pereira Chemical Engineering Program COPPE Federal University of Rio de Janeiro Rio de Janeiro Brazil

Maheswari Purushothaman Department of Chemistry SRM Valliammai Engineering College SRM Nagar Kattankulathur Tamilnadu India

Bidhan Chandra Ruidas Department of Chemical Engineering Birla Institute of Technology Mesra Ranchi Jharkhand India

Guru Charan Sahu Department of Chemistry Ranchi University Ranchi Jharkhand India

A.B. Sathya Department of Biotechnology Aarupadai Veedu Institute of Technology Chennai Tamilnadu India

Rahul Sharma Department of Chemistry Sabarmati University Ahmedabad Gujarat India

Rahul Sharma AcSIR CSIR‐National Physical Laboratory New Delhi India

Nidhi Singh Centre of Bioinformatics University of Allahabad Prayagraj Uttar Pradesh India

Veer Singh School of Biochemical Engineering IIT (BHU) Varanasi Uttar Pradesh India

R. Sivashankar Department of Chemical Engineering Hindustan Institute of Technology and Science Chennai Tamilnadu India

Arunachalam Thirunavukkarasu Department of Industrial Biotechnology Government College of Technology Coimbatore Tamilnadu India

Amit Kumar Tiwari Department of Chemical Engineering Birla Institute of Technology Mesra Ranchi Jharkhand India

Srihari Vedartham NICMAR Hyderabad Campus at Shamirpet Hyderabad Telangana India

Shashikant Shivaji Vhatkar Department of Nanoscience and Technology Central University of Jharkhand Brambe Ranchi Jharkhand India

Priyanka Yadav School of Biochemical Engineering IIT (BHU) Varanasi Uttar Pradesh India

Preface

Today, pollution due to various anthropogenic activities has increased many times. Organic and inorganic pollutants are the most significant problem that humanity currently faces in the broad categories of water pollutants. Although several measures have been proposed and implemented to reduce these pollutants, their increasing concentration in bodies of water has created serious concerns. Over the years, the problem has been aggravated by uncontrolled industrialization and urbanization and the consequent alteration of humanity's natural resources. The direct discharge of wastewater contaminants and their geographical mobilization have led to increased concentrations in ground, surface, and residual waters. Therefore, it is essential to understand this problem today and to control the source. In addition, extensive knowledge of detection and disposal methods is needed to develop technological solutions for various environments, including urban, rural, and urban areas.

The purpose of this book is to provide an information platform about wastewater contaminants in the current context, where researchers, engineers, and technologists working in this field face various challenges. Conventional physicochemical techniques used to remove contaminants from wastewater include ion exchange, precipitation, degradation, coagulation, coating, membrane processes, and adsorption. However, these applications have technological and economic limitations. Biomass‐related precursors for the preparation of biosorbents are attracting increasing attention from researchers. Different activation approaches are used in addition to native biomass utilizations. This book deliberately minimizes basic information and focuses on sources of water pollution, biomass for biosorbent preparation, characterization of biosorbents, understanding associated biosorption mechanisms, modeling analyses of biosorption, sustainable approaches for biosorption applications, and possibilities for recovering precious metals. This book will be a key guide for environmental engineers, researchers, water authorities, and students in these fields.

Rangabhashiyam SelvasembianPardeep Singh

Foreword

I am extremely pleased to provide the foreword to a book on biosorption that deals with the fundamentals, advancements, and future possibilities of this exciting technology. Biosorption employs the ability of biomass to adsorb different contaminants through various physicochemical mechanisms. A wide variety of biosorbents of different origins have been recognized to have high sorption capacity toward various contaminants. Biosorption mechanisms have been explored by scientists to obtain a basic understanding of the process. Nevertheless, biosorption has seldom been used for real industrial applications. The reasons are many and include lack of experimentation on real industrial effluents, multi‐component studies, and surface functionalization. Thus, a thorough compilation of the biosorption literature and a solid understanding of the biosorption technology’s essentials, progress, and potential are needed. This book, Biosorption for Wastewater Contaminants, offers the complete package.

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