Food Chemistry

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FOOD CHEMISTRY
A unique book detailing the impact of food adulteration, food toxicity and packaging on our nutritional balance, as well as presenting and analyzing technological advancements such as the uses of green solvents with sensors for non-destructive quality evaluation of food.
Audience Food Chemistry: The Role of Additives, Preservatives and Adulteration

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• May aid in weight control.

Natural non-nutritive sweeteners are present in nature. Some of the examples of natural non-nutritive sweeteners are listed in Table 2.4.

Table 2.4 List of natural non-nutritive sweeteners.

Sweetener Source Chemical nature Potency FDA approval
Brazzein, Pentadin West African Fruit Oubli Protein 500–2,000 Not Approved
Neohesperidin dihydrochalcone A derivative of the bitter constituent of grapefruit Glycoside 300–1,800 Not Approved
Glycyrrhizin Root of Liquorice Glycoside 30–50 Not Approved
Thaumatin Katemfe fruit Protein 2,000 Not Approved
Stevia Leaves of Stevia rebaudiana Glycoside 300 Approved
Curculin Malaysian fruit Curculigo latifolia Protein 430–2,070 Not Approved
Inulin Various Plants Polysaccharide 10% of Sucrose Not Approved
Mabinlin Seed of a Chinese plant Mabinlang Protein 100–400 Not Approved
Miraculin Fruit of Synsepalum dulcificum Glycoprotein modifies taste receptors Not Approved
Monatin Plant Sclerochiton ilicifolius Indole derivative 3,000 Not Approved
Monellin Fruit of West african shrub Dioscoreophyllum cumminsii Protein 800–2,000 Not Approved
Osladin Rhizome of Polypodium vulgare Saponin 500 Not Approved
Luo han guo Fruits of Siraitia grosvenorii Glycosides 300 Approved

2.3.6.6.3 Artificial Non-Nutritive Sweeteners

They are derived from the chemical synthesis of organic compounds. These compounds may or may not be found in nature. A list of artificial non nutritive sweeteners along with their potency and use are listed in Table 2.5. New artificial sweeteners are researched. These compounds are lowcost product and can be synthesized easily. So, in future, they will be the primary sweetening compound [19].

Table 2.5 List of artificial non-nutritive sweeteners.

Chemical name of sweetener Trade name of the sweetener Potency Caloric value (cal/g) Use
Acesulfame Sunett, Sweet One 200 times sweeter than sugar 0 Used in different candies, desserts, baked goods.
Aspartame Nutra Sweet 180–200 times sweeter than sugar 4 Used in soft drinks, chewing gum, frozen desserts, pharmaceuticals.
Neotame - 8,000–13,000 times sweeter than sugar 0 Used in beverage, dairy products, baked goods, gums.
Saccharin Sweet and Low, Sweet Twin, Sugar Twin, 300–700 times sweeter than sugar 0 Used in beverages and sometimes used together with aspartame.
Sucralose Splenda 600 times sweeter than sugar 0 Used in frozen desserts, cookies, candies, baked products.

2.3.6.7 Leavening Agent

These types of additives are added to increase the surface area of a dough or batter by creation of gas bubbles inside the dough or batter. They also make the product light in weight. During the baking process, the gas bubbles get expanded so volume of the product increases and a desirable porous structure is obtained. The functions of leavening agents are as follows:

1 1. It makes the final product light and spongy.

2 2. It makes the product digestible.

3 3. It makes it soft.

4 4. It makes the product tastier and appetizing.

The leavening agents used as additives are mainly of two types.

a. Biological agent: Biological leavening agents are harmless microorganism like yeast Saccharomyces cerevisiae. The yeast cell added ferments the sugar and produces carbon dioxide and ethanol. The yeast added may be active dry yeast or compressed yeast.

b. Chemical agents: Three types of chemical leavening agents are used. They are baking soda, baking powder, and ammonium bicarbonate. Baking soda contains sodium bicarbonate (NaHCO3) that releases carbon di oxide when heated. Baking soda is always used with acid like buttermilk, vinegar, lemon juice, molasses, honey, vinegar, buttermilk, cocoa fruits, fruit juices, and cream of tartar. Baking powder contains baking soda, dry acids, and starch. Baking powder may be either single acting powder or double acting powder. In single acting baking powder carbon dioxide is released as soon as it is added in the liquid. Double acting baking powder releases carbon dioxide in two stage: first is when it is mixed in cold liquid and second is during baking. Ammonium bicarbonate is another leavening agent that produces carbon dioxide when it decomposes. They are used in the products which are finally dry and porous so that all the ammonia liberated during heating gets released otherwise it will affect the taste.

2.3.6.8 Firming Agent

These are the additives that give firming action to food. Fruits and vegetables contain pectin that is relatively insoluble and form firm gel around the tissues of fruit. Firming agents are additives that help to precipitate residual pectin. It strengthens the supporting tissue and prevent its collapse during processing. Calcium salts are used as firming agent. It forms calcium pectate gel that protects the tissues against softening during processing. Some of the other examples of firming agents include aluminium sulfate, ammonium aluminium sulfate, calcium chloride, calcium sulfate, and sodium/potassium aluminium sulfate.

2.3.6.9 Glazing Agent

Food glazing agents are additives also known as polishing agent. When they are applied on food material, it gives a protective and shiny coating on fruits, bakery and confectionary items. These additives are prepared from either natural or synthetic sources. Common glazing agents are beeswax, lac, mineral oil, etc.

2.3.6.10 Humectant

These are hygroscopic substances that promote moisture retention. It prevents the food from drying out. Polyols including propylene glycol, glycerol, sorbitol, and mannitol are some examples of humectants. They contain several hydroxyl groups that makes them hydrophilic that enables them to bind with water. They are also known as moisture retention agent or wetting agent. Examples of products where humectants are used include shredded coconut, cookies, glazed and dried fruit, and cake.

2.3.6.11 Sequestering Agent

Sequestering agents are also known as chelating agent. They protect food products from chemical, oxidative, and enzymatic reactions that promote deterioration of food through chelation during processing and storage. They form chelate with polyvalent metal ions like copper, iron, and nickel. Even at very low concentration of these metal ions as low as 0.05 ppm, they can cause rancidity, discoloration, spoilage in texture, odor, and flavor. Copper can affect ascorbic acid, folic acid, vitamin E, and thiamine. Vitamin A will be destroyed by both copper and iron. Fats and oils are also oxidized in presence of metal ions that act as catalyst. Examples of chelating agents are EDTA, polyphosphate, citric acid, and tartaric acid.

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