Salah Belaadi - Thermodynamic Processes 2

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Thermodynamic Processes 2 is devoted to the study of equilibrium between phases in the case of the four changes of physical state: fusion, boiling or vaporization, sublimation and allotropy or transition. It also includes a section that addresses energy's relationship to the zero sum aspect of exergy and thermal cycles. This second volume presents scientific and technical examples – both theoretical and industrial – which are the result of a careful selection, accrued over more than three decades of teaching thermodynamics and in collaboration with the industry sector. The didactic exercises and the practical problems are entirely dedicated to the understanding of this science, and the potential applications for the industrial world. This book is a tool for work and reflection essential for the student in training, as well as the engineer or experienced researcher.

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In memory of my parents

Series Editor

Jean-Claude Charpentier

Thermodynamic Processes 2

State and Energy Change Systems

Salah Belaadi

First published 2020 in Great Britain and the United States by ISTE Ltd and - фото 4

First published 2020 in Great Britain and the United States by ISTE Ltd and John Wiley & Sons, Inc.

Apart from any fair dealing for the purposes of research or private study, or criticism or review, as permitted under the Copyright, Designs and Patents Act 1988, this publication may only be reproduced, stored or transmitted, in any form or by any means, with the prior permission in writing of the publishers, or in the case of reprographic reproduction in accordance with the terms and licenses issued by the CLA. Enquiries concerning reproduction outside these terms should be sent to the publishers at the undermentioned address:

ISTE Ltd

27-37 St George’s Road

London SW19 4EU

UK

www.iste.co.uk

John Wiley & Sons, Inc.

111 River Street

Hoboken, NJ 07030

USA

www.wiley.com

© ISTE Ltd 2020

The rights of Salah Belaadi to be identified as the author of this work have been asserted by him in accordance with the Copyright, Designs and Patents Act 1988.

Library of Congress Control Number: 2019953627

British Library Cataloguing-in-Publication Data

A CIP record for this book is available from the British Library

ISBN 978-1-78630-514-5

Foreword 1

Circular Economy and Engineering

Circular economy and engineering: process thermodynamics as an essential chemical engineering tool for the design and control of the processes encountered in the factory of the future within the framework of Industry 4.0

Process engineering involves the sciences and technologies that optimally transform matter and energies into products required by a consumer and into nonpolluting wastes. Today, it takes part in the framework of circular economy and engineering (monitoring of products and processes from cradle to grave), and the optimal transformations of matter and energies must be carried out to design the factory of the future, taking into account the emergence of Industry 4.0 and the voluminous amount of data ( Big Data movement ).

Modern (green) process engineering is deliberately oriented toward process intensification (i.e., producing much more and better, with use of much less resources). This involves a physical-chemistry multidisciplinary and multiscale approach to modelling and computer simulation, in terms of time and space, from the atomic and molecular scales. This involves the equipment and the reactor scales, up to the scales of the overall factory (i.e., the design of a refinery, a chemical, a textile or a cement complex plant from Schrödinger equations).

To meet this multidisciplinary and multiscale approach, the preponderant and irreplaceable concept and background of chemical thermodynamics appears in all its splendour, and more generally, this concerns the thermodynamics of processes for the multiscale control of these processes.

It is clear that studies that discuss thermodynamics of processes must cover chemical thermodynamics (open or closed systems with or without chemical reaction, phase equilibrium) and the energetics of processes (thermal cycles, heat pump, degraded energy, exergy). However, these studies must also be illustrated with examples of real multiscale physicochemical applications. This will prepare or help or contribute to the design, the development and the control of the processes that will be encountered in the factory of the future, by means of methodologies and techniques to obtain reliable thermodynamic data that will contribute to the abundance of data ( Big Data/Industry 4.0 ).

A big thank you to Professor Salah Belaadi, leading expert in education and research in the field of thermodynamics of processes, for offering such an instructional and didactic book, whose chapters mainly present exercises oriented towards industrial applications.

This book on thermodynamics and energetics of processes is a guide (a vademecum ), which I am personally convinced will be of great benefit to a large number of university teachers and researchers, and engineers and technicians active in today’s economy sector, as well in the very near future.

Jean-Claude CHARPENTIER

Former director of ENSIC Nancy and ESCPE Lyon, France

Former president of the European Federation of Chemical Engineering

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