Johann Beckmann - A History of Inventions, Discoveries, and Origins, Volume II (of 2)

Mirrors of copper, brass and gold, I have found mentioned only by the poets, who perhaps employed the names of these metals because they best suited their measure, or because they wished to use uncommon expressions, and thought a golden mirror the noblest. By the brass ones perhaps are to be understood only such as were made of mixed copper. Did golden mirrors occur oftener, I should be inclined to refer the epithet rather to the frame or ornaments than to the mirror itself; for at present we say a gold watch, though the cases only may be of that metal.

Mirrors seem for a long time to have been made of a mixture of copper and tin, as is expressly said by Pliny 153 153 Lib. xxxiii. c. 9. p. 627, and lib. xxxiv. c. 17, p. 669. , who adds, that the best were constructed at Brundisium. This mixture, which was known to Aristotle, produces a white metal, which, on account of its colour, may have been extremely proper for the purpose, and even at present the same mixture, according to the careful experiments made by Mr. Mudge, an Englishman 154 154 Philosophical Transactions, vol. lxvii. p. 296. , produces the best metal for specula. It appears that the ancients had not determined the proportion very accurately; for Pliny assures us twice that in his time mirrors of silver were preferred. It is indeed not easy to ascertain the quantity of each metal that ought to be taken, and the most advantageous degree of heat; upon which a great deal depends. One of the principal difficulties is to cast the metal without blisters or air-holes, and without causing any part of the tin to oxidize, which occasions knots and cracks, and prevents it from receiving a fine polish. A passage of Lucian 155 155 Quomodo Historia sit conscrib. cap. 51, Bipont edition, iv. p. 210, 535. Commentators have found no other way to explain κέντρον (a word which occurs in Lucian’s description of the mirror), than by the word centre , to which, according to their own account, there can be here no allusion. In my opinion κέντρον signifies those faulty places which are not capable of a complete polish, on account of the knots or cracks which are found in them. Lucian therefore speaks of a faultless mirror which represents the image perfect, as he afterwards informs us. , which no one as yet has been able to clear up, alludes certainly, in my opinion, to these faults. A mixture of copper and tin is so brittle, that it is very liable to crack; and a mirror formed of it, if not preserved with great care, soon becomes so dim, that it cannot be used till it has been previously cleaned and polished. For this reason a sponge with pounded pumice-stone was generally suspended, from the ancient mirrors, and they were kept likewise in a case or box, as may be seen by the greater part of those still extant. Mirrors of silver were less subject to this inconvenience, and I am inclined to think that the latter on this account made the former be disused, as we are informed by Pliny.

As ancient mirrors of metal are still to be found in collections of antiquities, it might be of some importance to the arts if chemical experiments were made on their composition. Those who have hitherto given us any account of them have contented themselves with describing their external figure and shape. Count Caylus 156 156 As the account of these experiments is given only in an expensive work, which may not often fall into the hands of those who are best able to examine it, I insert it here. “The ancient mirror, which I examined, was a metallic mixture, very tender and brittle, and of a whitish colour inclining to grey. When put into the fire, it remained a long time in a state of ignition before it melted. It was neither inflammable nor emitted any smell like garlic, which would have been the case had it contained arsenic. It did not either produce those flowers which are generally produced by all mixtures in which there is zinc. Besides, the basis of this mixture being copper, it would have been of a yellow colour had that semi-metal formed a part of it. I took two drams of it and dissolved them in the nitrous acid. A solution was speedily formed, which assumed the same colour as solutions of copper. It precipitated a white powder, which I carefully edulcorated and dried. Having put it into a crucible with a reductive flux, I obtained lead very soft and malleable. is the only person, as far as I know, who caused any chemical experiments to be undertaken on this subject. They were made on a mirror found near Naples, by M. Roux, who asserts that the composition was a mixture of copper and regulus of antimony, with a little lead. Antimony however was not known to the ancients. If that metal was really a component part, the mirror must have been the work of more modern times, or it must be allowed that the artist had metal combined with antimony without knowing it; but the latter is not probable. The experiments made by Roux do not seem to me to have proved in a satisfactory manner the presence of regulus of antimony; moreover, no certain information can be derived from them, for the antiquity of the mirror was not ascertained; nor was it known whether it ought to be reckoned amongst the best or the worst of the period when it was made.

Those mirrors, which were so large that one could see one’s self in them at full length, must, in all probability, have consisted of polished plates of silver; for to cast plates of such a size of copper and tin would have required more art than we can allow to those periods; and I do not know whether our artists even now would succeed in them 157 157 Of such large mirrors Seneca speaks in his Quæst. Nat. lib. i. Of the like kind was the mirror of Demosthenes mentioned by Plutarch, Lucian, and Quintilian. – Institut. Orat. xi. 3, 68, p. 572. “Having filtered the solution, I took a part of it, upon which I poured an infusion of gall-nuts, but it produced no change. A solution of gold, which I poured upon another part, made it assume a beautiful green colour; but no precipitate was formed: which is sufficient to prove that there was neither iron nor tin in the mixture. “On the remaining part of the solution I poured a sufficient quantity of the volatile alkali to dissolve all the copper that might be contained in it. The solution became of a beautiful sapphire blue colour, and a white precipitate was formed. Having decanted the liquor, and carefully edulcorated the precipitate, I endeavoured to reduce it; but whether it was owing to the quantity being too small, or to my not giving it sufficient heat, I could not succeed. I had recourse therefore to another method. “I took the weight of two drams of the mixture, which I brought to a high state of ignition in a cuppel. When it was of a whitish-red colour, I threw upon it gradually four drams of sulphur, and when the flame ceased, I strengthened the fire in order to bring it to complete fusion. By these means I obtained a tender brittle regulus, whiter than the mixture, in which I observed a few small needles. Being apprehensive that some copper might still remain, I sulphurated it a second time, and then obtained a small regulus which was almost pure antimony. “It results from these experiments, that the metal of which the ancients made their mirrors was a composition of copper, regulus of antimony, and lead. Copper was the predominant, and lead the smallest part of the mixture; but it is very difficult, as is well known, to determine with any certainty the exact proportion of the substances contained in such compositions.” [In the examination of an Etruscan mirror, which was placed in my hands for analysis by Professor Gerhardt of Berlin, it was found to consist, in 100 parts, of 67·12 copper, 24·93 tin, and 8·13 lead, approximating closely to an alloy of eight parts of copper to three of tin and one of lead. The oxide of tin obtained in the course of analysis was carefully examined, before the blowpipe, for antimony, but I did not succeed in detecting a trace of that metal. A similar mirror had been likewise analysed by Klaproth; he found 62 per cent. copper, 32 tin, and 6 per cent. lead, but no trace of antimony. – W. F.] .